CAJ | 학술논문

在水热条件下,以1,6-己二胺为模板剂合成了一个三维(3D)亚磷酸锌无机-有机杂化化合物(C6 N2 H16)0.5 ZnHPO3(ZnHPO-CJ15),并对其单晶结构进行了解析.结果表明, ZnHPO-CJ15晶体属单斜晶系, P21/ c 空间群, a =1.19587(7) nm, b =0.82766(5) nm, c =0.77756(5) nm,α=90.00°,β=95.8370(10)°,γ=90.00°, V =0.76562(8) nm3, Z =1. ZnHPO-CJ15具有层柱状结构,其骨架结构是由ZnO3 N 四面体和 HPO3假四面体连接构成的二维4×8元环网层结构,层与层之间由1,6-己二胺分子与 Zn 配位柱撑连接形成三维结构.
재수열조건하,이1,6-기이알위모판제합성료일개삼유(3D)아린산자무궤-유궤잡화화합물(C6 N2 H16)0.5 ZnHPO3(ZnHPO-CJ15),병대기단정결구진행료해석.결과표명, ZnHPO-CJ15정체속단사정계, P21/ c 공간군, a =1.19587(7) nm, b =0.82766(5) nm, c =0.77756(5) nm,α=90.00°,β=95.8370(10)°,γ=90.00°, V =0.76562(8) nm3, Z =1. ZnHPO-CJ15구유층주상결구,기골가결구시유ZnO3 N 사면체화 HPO3가사면체련접구성적이유4×8원배망층결구,층여층지간유1,6-기이알분자여 Zn 배위주탱련접형성삼유결구.
A 3D inorganic-organic hybrid zinc phosphite (C6 N2 H16 ) 0. 5 ZnHPO3(ZnHPO-CJ15) has been hy-drothermally synthesized. Crystal data for ZnHPO-CJ15 are as follows: monoclinic system, P21 / c space group, a =1. 19587 nm, b = 0. 82766(5) nm, c = 0. 77756(5) nm, α = 90. 00°, β = 95. 8370(10)°, γ =90. 00°, V=0. 76562(8) nm3 and Z =1. Single-crystal structure analysis reveals that the inorganic framework of ZnHPO-CJ15 is constructed by the connection of HPO3 pseudo-pyramids and ZnO3 N tetrahedral to form 2D layers with 4- and 8-rings. The 1,6-hexanediamine molecules act as the pillars to link the adjacent zinc phos-phite layers via N-Zn bonds to form 3D framework.