CAJ | 학술논문

利用中国石油石化院75 kg/h聚丙烯中试装置进行进口Basell ZN M1催化剂的聚合反应性能评价实验。聚合结果表明， ZN M1催化剂具有较高的聚合活性和氢调敏感性，产品的等规度可以在较大范围调整，催化活性的释放平稳，抗杂质干扰能力强。在催化剂流量和质量浓度分别为0.18 mL/min及100 g/L， n（氢气）/n（丙烯）为0.004， m（三乙基铝）/m（给电子体）为1.08的工艺条件下，当丙烯的含水量为3.54 mg/L时， ZN M1催化剂的活性[ m（聚丙烯）/m（催化剂）]高达29654。
이용중국석유석화원75 kg/h취병희중시장치진행진구Basell ZN M1최화제적취합반응성능평개실험。취합결과표명， ZN M1최화제구유교고적취합활성화경조민감성，산품적등규도가이재교대범위조정，최화활성적석방평은，항잡질간우능력강。재최화제류량화질량농도분별위0.18 mL/min급100 g/L， n（경기）/n（병희）위0.004， m（삼을기려）/m（급전자체）위1.08적공예조건하，당병희적함수량위3.54 mg/L시， ZN M1최화제적활성[ m（취병희）/m（최화제）]고체29654。
The reaction performance of import catalyst ZN M 1 was evaluated in the 75 kg/h polypropylene pilot unit of Lanzhou Petrochemical Research Center.The results showed that catalyst ZN M 1 had higher activity and better hydrogen response behavior , tolerance to impurities and activity stability.The isotacticity of the product could be adjusted in a wide range.Under the conditions of catalyst flow 0.18 mL/min, catalyst mass concentration 100 g/L, the mass ratio of triethyl aluminum to electro donor 1.08, the activity [m(polypropylene)/m(catalyst)]of ZN M1 reached 29 654 when the moisture in propylene was 3.54 mg/L.