功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
11期
11061-11065,11070
,共6页
曹亚超%李明伟%潘翠连%朱廷霞%尹华伟%程旻
曹亞超%李明偉%潘翠連%硃廷霞%尹華偉%程旻
조아초%리명위%반취련%주정하%윤화위%정민
ZTS晶体%法向生长速度%动力学%L-丙氨酸%化学侵蚀法
ZTS晶體%法嚮生長速度%動力學%L-丙氨痠%化學侵蝕法
ZTS정체%법향생장속도%동역학%L-병안산%화학침식법
ZTS crystal%normal growth rate%growth kinetics%L-alanine%chemical etching
通过对 L-丙氨酸掺杂下 ZTS(100)、(010)及(001)面法向生长速度的研究发现,各晶面法向生长速度随过饱和度的增加而线性增加;随掺杂浓度的增加,(100)面的法向生长速度先增大后减小,而(010)及(001)面的法向生长速度先减小,接着增大,然后又减小。分析表明(100)面以位错生长机制为主,(010)及(001)面以连续生长机制为主。利用光学显微镜在侵蚀后的(100)面观察到矩形位错蚀坑,蚀坑密度为33~308 mm-2;掺杂浓度为1%(摩尔分数)时,蚀坑密度最小。
通過對 L-丙氨痠摻雜下 ZTS(100)、(010)及(001)麵法嚮生長速度的研究髮現,各晶麵法嚮生長速度隨過飽和度的增加而線性增加;隨摻雜濃度的增加,(100)麵的法嚮生長速度先增大後減小,而(010)及(001)麵的法嚮生長速度先減小,接著增大,然後又減小。分析錶明(100)麵以位錯生長機製為主,(010)及(001)麵以連續生長機製為主。利用光學顯微鏡在侵蝕後的(100)麵觀察到矩形位錯蝕坑,蝕坑密度為33~308 mm-2;摻雜濃度為1%(摩爾分數)時,蝕坑密度最小。
통과대 L-병안산참잡하 ZTS(100)、(010)급(001)면법향생장속도적연구발현,각정면법향생장속도수과포화도적증가이선성증가;수참잡농도적증가,(100)면적법향생장속도선증대후감소,이(010)급(001)면적법향생장속도선감소,접착증대,연후우감소。분석표명(100)면이위착생장궤제위주,(010)급(001)면이련속생장궤제위주。이용광학현미경재침식후적(100)면관찰도구형위착식갱,식갱밀도위33~308 mm-2;참잡농도위1%(마이분수)시,식갱밀도최소。
Via studying the normal growth rates of the (100),(010)and (001)faces of ZTS crystal under differ-ent doping concentrations of L-alanine,we found that the normal growth rate of ZTS crystal increased linearly with the increase of supersaturation.With increase of doping concentration,L-alanine addition led to an initial increase and then a decrease of the normal growth rate of the (100)face.However,L-alanine doping led to a de-crease first,followed by an increase and then a decrease again of the normal growth rates of the (0 1 0 )and (001)faces.The growth of (100)face was featured mainly by the dislocation mechanism,and the growth of (010)and (001)faces are,however,featured by the continuous growth model as supported by the experimental results.Well-defined dislocation pits of rectangular shape were observed on the chemical etching (100)face of ZTS crystal by using optical microscopy.The dislocation density of (100)face was 33-308 mm-2 .Study results indicated that dislocation density could be minimized when L-alanine concentration was set at 1 mol%.