材料研究与应用
材料研究與應用
재료연구여응용
MATERIALS RESEARCH AND APPLICATION
2014年
1期
30-34
,共5页
张普%袁鸽成%秦典成%袁潜%骆志捷
張普%袁鴿成%秦典成%袁潛%駱誌捷
장보%원합성%진전성%원잠%락지첩
搅拌摩擦焊%6005A铝合金%剥落腐蚀%电化学阻抗谱
攪拌摩抆銲%6005A鋁閤金%剝落腐蝕%電化學阻抗譜
교반마찰한%6005A려합금%박락부식%전화학조항보
friction stir welding%6005A aluminum alloys%exfoliation corrosion%electrochemical impedance spectroscopy
采用搅拌摩擦焊机焊接6005 A铝合金型材,获得无缺陷焊缝。借助电化学工作站、扫描电子显微镜及金相显微镜等对比研究了焊缝及母材的剥落腐蚀行为。研究结果表明,母材发生的是晶间腐蚀且部分区域发生剥落,焊缝则只发生了均匀点蚀;腐蚀评级和电化学阻抗谱都说明焊缝比母材具有更强的耐剥蚀性。通过对微观组织的对比分析,得出焊缝耐剥蚀性能提高的原因是在焊接过程中发生了动态再结晶,使母材中的带状晶粒转变成了等轴细小晶粒;同时,晶界上的第二相粒子发生固溶后,使其在晶界与晶内的分布趋于均匀从而减弱了微电偶腐蚀倾向。
採用攪拌摩抆銲機銲接6005 A鋁閤金型材,穫得無缺陷銲縫。藉助電化學工作站、掃描電子顯微鏡及金相顯微鏡等對比研究瞭銲縫及母材的剝落腐蝕行為。研究結果錶明,母材髮生的是晶間腐蝕且部分區域髮生剝落,銲縫則隻髮生瞭均勻點蝕;腐蝕評級和電化學阻抗譜都說明銲縫比母材具有更彊的耐剝蝕性。通過對微觀組織的對比分析,得齣銲縫耐剝蝕性能提高的原因是在銲接過程中髮生瞭動態再結晶,使母材中的帶狀晶粒轉變成瞭等軸細小晶粒;同時,晶界上的第二相粒子髮生固溶後,使其在晶界與晶內的分佈趨于均勻從而減弱瞭微電偶腐蝕傾嚮。
채용교반마찰한궤한접6005 A려합금형재,획득무결함한봉。차조전화학공작참、소묘전자현미경급금상현미경등대비연구료한봉급모재적박락부식행위。연구결과표명,모재발생적시정간부식차부분구역발생박락,한봉칙지발생료균균점식;부식평급화전화학조항보도설명한봉비모재구유경강적내박식성。통과대미관조직적대비분석,득출한봉내박식성능제고적원인시재한접과정중발생료동태재결정,사모재중적대상정립전변성료등축세소정립;동시,정계상적제이상입자발생고용후,사기재정계여정내적분포추우균균종이감약료미전우부식경향。
The 6005A aluminum alloy extrusions defect-free joints were obtained by friction stir welding . By means of electrochemical workstation ,scanning electron microscope and metallographic microscope , the exfoliation corrosion properties of both 6005A aluminum’s weld-joints and base materials were investi-gated comparatively .The results showed that the pitting occured uniformly on the surface of joints ,while severe inter-granular corrosion appeared in base material and even delaminate in some parts of base materi-al .Both the rating of corrosion and electrochemical impedance spectroscopy suggested that the joints have better exfoliation corrosion resistance .Dynamic recrystallization happened in the joints during welding process ,thus making the lengthened and narrow grains being turned into equiaxed-fine ones ,meanw hile , the second-phase precipitation occured on the grain boundary ,resulting in its uniformity between grain boundary and intra-crystal ,w hich reduced the tendency of the galvanic corrosion correspondingly .