精细与专用化学品
精細與專用化學品
정세여전용화학품
FINE AND SPECIALTY CHEMICALS
2012年
11期
26-29
,共4页
自乳化%水性环氧树脂%乳液稳定性%树脂固化物%黏接强度
自乳化%水性環氧樹脂%乳液穩定性%樹脂固化物%黏接彊度
자유화%수성배양수지%유액은정성%수지고화물%점접강도
self-emulsified%waterborne epoxy resin%emulsion stability%cured epoxy resin%adhesive strength
使用环氧树脂6002分别与不同分子量的聚乙二醇（PEG1000或PEG2000）反应合成出自乳化型水性环氧树脂（WEP1000与WEP2000）,并将其与环氧树脂6002按照不同的比例配制成乳液,再加入大分子聚胺类XCT-802固化剂组成水性环氧树脂黏合剂。考察了不同的WEP、用量及其他表面活性剂对环氧树脂6002乳液的稳定性以及固化物的黏接强度的影响。结果表明：当m（WEP1000）：m（EP6002）=15：85、其含量为乳液的50%、预糊化淀粉为3%时配成的乳液具有良好的稳定性,且与大分子聚胺类XCT-802固化剂形成的固化物也具有最高的黏接强度。
使用環氧樹脂6002分彆與不同分子量的聚乙二醇（PEG1000或PEG2000）反應閤成齣自乳化型水性環氧樹脂（WEP1000與WEP2000）,併將其與環氧樹脂6002按照不同的比例配製成乳液,再加入大分子聚胺類XCT-802固化劑組成水性環氧樹脂黏閤劑。攷察瞭不同的WEP、用量及其他錶麵活性劑對環氧樹脂6002乳液的穩定性以及固化物的黏接彊度的影響。結果錶明：噹m（WEP1000）：m（EP6002）=15：85、其含量為乳液的50%、預糊化澱粉為3%時配成的乳液具有良好的穩定性,且與大分子聚胺類XCT-802固化劑形成的固化物也具有最高的黏接彊度。
사용배양수지6002분별여불동분자량적취을이순（PEG1000혹PEG2000）반응합성출자유화형수성배양수지（WEP1000여WEP2000）,병장기여배양수지6002안조불동적비례배제성유액,재가입대분자취알류XCT-802고화제조성수성배양수지점합제。고찰료불동적WEP、용량급기타표면활성제대배양수지6002유액적은정성이급고화물적점접강도적영향。결과표명：당m（WEP1000）：m（EP6002）=15：85、기함량위유액적50%、예호화정분위3%시배성적유액구유량호적은정성,차여대분자취알류XCT-802고화제형성적고화물야구유최고적점접강도。
Two kinds of self-emulsified waterborne epoxy resins(WEP1000 and WEP2000) were synthesized by the reaction of epoxy resin(EP6002) with different molecular weight polyethylene glycol(PEG1000 or PEG2000),which were then used to prepare emulsions by emulsified with different proportions of epoxy resin.An adhesive was prepared when the resulting epoxy resin emulsions mixed with polyamine type XCT-802 curing agent.The effects of different WEP,their addition amounts and other surfactants on the stability of the emulsions were observed,and adhesive strength of the cured epoxy resin from these emulsions was investigated.The results showed that the emulsion containing 3% pregelatinized strach and 50% blend resin possessed better stability when the ratio of m(WEP1000):m(EP6002) was equal to 15:85 in this blend.The cured epoxy resin from the emulsion containing XCT-802 curing agent possessed the best adhesive strength.
