吉林化工学院学报
吉林化工學院學報
길림화공학원학보
JOURNAL OF JILIN INSTITUTE OF CHEMICAL TECHNOLOGY
2012年
11期
36-38
,共3页
沈启慧%刘岩%孙淑珍%高文秀
瀋啟慧%劉巖%孫淑珍%高文秀
침계혜%류암%손숙진%고문수
微波%掺杂%CdS%Fe纳米晶体
微波%摻雜%CdS%Fe納米晶體
미파%참잡%CdS%Fe납미정체
Microwave%doping%CdS : Fe nanocrystals
在水溶液中,将Fe2+离子掺杂在CdS纳米晶体的内部,并利用微波辐射促进Fe2+离子向外扩散和纳米晶体的生长,制备出荧光发射波长在520~650nm范围内连续可调的CdS:Fe纳米晶体.掺杂纳米晶体具有立方闪锌矿结构,晶体结构完整,粒度分布系数为9.7%,并具有高达35%的荧光量子产率和良好的光化学稳定性.
在水溶液中,將Fe2+離子摻雜在CdS納米晶體的內部,併利用微波輻射促進Fe2+離子嚮外擴散和納米晶體的生長,製備齣熒光髮射波長在520~650nm範圍內連續可調的CdS:Fe納米晶體.摻雜納米晶體具有立方閃鋅礦結構,晶體結構完整,粒度分佈繫數為9.7%,併具有高達35%的熒光量子產率和良好的光化學穩定性.
재수용액중,장Fe2+리자참잡재CdS납미정체적내부,병이용미파복사촉진Fe2+리자향외확산화납미정체적생장,제비출형광발사파장재520~650nm범위내련속가조적CdS:Fe납미정체.참잡납미정체구유립방섬자광결구,정체결구완정,립도분포계수위9.7%,병구유고체35%적형광양자산솔화량호적광화학은정성.
The Fe (II) ions were doped into the CdS nanoerystals in the water solution, and they came outward under the microwave irradiation. With the growth of CdS : Fe nanocrystals, the fluorescence scope of doped nanocrystals shifted from 520 nm to 650 nm. The CdS : Fe nanocrystals had good cubic zinc blende structure and the coefficient of particle size distribution was 9.7%. Meanwhile, the quantum yield of CdS: Fe nanoerystals was near to 35% and chemical/photochemical stability of NCs were found to be excellent.