广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2012年
17期
39-40
,共2页
三氧化%铝%聚偏氟乙烯%复合膜%制备%农征
三氧化%鋁%聚偏氟乙烯%複閤膜%製備%農徵
삼양화%려%취편불을희%복합막%제비%농정
alumina%polyvinylidenefluoride%composite membrane: preparation: characterization
文章介绍了在聚偏氟乙烯铸膜液中添加了无机钠米Al2O3粒子,采用相转化法制备了Al2O3/PVDF复合中空纤维臌。使用电镜对膜的微观结构进行了分析,初步研究了无机粒子在膜孔形成的过程中所起的作用和机理。并且对膜的孔隙率、最大孔径、力学性能和截留率进行了分析。结果表明复合膜的性能与纯PVDF膜的相比有显著提高,最大孔径从0.75μm降至0.3μm,水通鼍和截留率分别从10.09L/m2h和19.12%提商到28.25L/m2h和71.00%,断裂应力从3.09MPa提高到3.41MPa。
文章介紹瞭在聚偏氟乙烯鑄膜液中添加瞭無機鈉米Al2O3粒子,採用相轉化法製備瞭Al2O3/PVDF複閤中空纖維臌。使用電鏡對膜的微觀結構進行瞭分析,初步研究瞭無機粒子在膜孔形成的過程中所起的作用和機理。併且對膜的孔隙率、最大孔徑、力學性能和截留率進行瞭分析。結果錶明複閤膜的性能與純PVDF膜的相比有顯著提高,最大孔徑從0.75μm降至0.3μm,水通鼉和截留率分彆從10.09L/m2h和19.12%提商到28.25L/m2h和71.00%,斷裂應力從3.09MPa提高到3.41MPa。
문장개소료재취편불을희주막액중첨가료무궤납미Al2O3입자,채용상전화법제비료Al2O3/PVDF복합중공섬유고。사용전경대막적미관결구진행료분석,초보연구료무궤입자재막공형성적과정중소기적작용화궤리。병차대막적공극솔、최대공경、역학성능화절류솔진행료분석。결과표명복합막적성능여순PVDF막적상비유현저제고,최대공경종0.75μm강지0.3μm,수통타화절류솔분별종10.09L/m2h화19.12%제상도28.25L/m2h화71.00%,단렬응력종3.09MPa제고도3.41MPa。
The method of preparing theAl2O3/PVDF hollow fiber membrane by phase transition process, with adding the inorganic nano-particle γ-Al2O3 into the casting solution, was introduced in the paper. The microstructure of the membrane was also researched with the application of SEM. The porosity, max pore size, mechanical performance and rejection of the membrane were also characterized and it was found that its max pore size reduced from 0.75 μm to 0.39 μm, the pure water flux and rejection ratio increased from 10.09 L/m2.h, 19.12 % to 28.25 L/m2.h, 71.00 %. And the mechanical performance of the membrance was improved also. Keywords: alumina; polyvinylidenefluoride: composite membrane: preparation: characterization