CAJ | 학술논문

以纳米碘化亚铜、碘化钾和N，N＇-二甲基乙二胺为组合催化剂体系，以无毒的廉价易得的亚铁氰化钾为氰源，水为溶剂，对一系列芳基溴化物进行氰基化反应，高收率得到了相应的精细化学中间体芳香腈类化合物，反应条件温和，操作简单，并且经济环保。
이납미전화아동、전화갑화N，N＇-이갑기을이알위조합최화제체계，이무독적렴개역득적아철청화갑위청원，수위용제，대일계렬방기추화물진행청기화반응，고수솔득도료상응적정세화학중간체방향정류화합물，반응조건온화，조작간단，병차경제배보。
Cul-nanoparticles-catalyzed cyanation of aryl bromides under mild conditions has been developed with K4 [Fe(CN)6] as the cyanation reagent using water as the solvent in the presence of KI and N,N'-dimethylethyl- enediarnine. This method was applicable to a wide range of substrates and more economical and environmentally friendly.