CAJ | 학술논문

文章利用衰减全反射-傅立叶变换红外光谱（ATR-FTIR）技术对两种不同变质程度煤样进行显微组分结构分析，研究了低温氧化对煤炭粘结影响的机理。研究结果表明：低温氧化导致煤粘结指数和挥发份降低。同等氧化条件下，变质程度低的煤的粘结指数下降幅度大于变质程度高的煤。镜质组和壳质组结构中含有的环烷烃和脂肪烃以及活泼羟基的比例较多，是易受氧化的活性组分，煤样中镜质组和壳质组的组分含量越多，氧化对煤样粘结性的影响越大。
문장이용쇠감전반사-부립협변환홍외광보（ATR-FTIR）기술대량충불동변질정도매양진행현미조분결구분석，연구료저온양화대매탄점결영향적궤리。연구결과표명：저온양화도치매점결지수화휘발빈강저。동등양화조건하，변질정도저적매적점결지수하강폭도대우변질정도고적매。경질조화각질조결구중함유적배완경화지방경이급활발간기적비례교다，시역수양화적활성조분，매양중경질조화각질조적조분함량월다，양화대매양점결성적영향월대。
The maceral of two different rank coal was determined using attenuated total reflectance coupled with fourier transform infrared spectroscopy (ATR-FTIR) to investigate the effect of low-temperature oxidization on coal cocking property. The results indicated that, low-temperature oxidization cause the decrease of coal cocking property and volatile. The cocking property of low-rank coal was more sensitive to low-temperature oxidization than high-rank coal. The cyclane, fatty hydrocarbon and active hydroxyl in vitrinite and exinite of coal were influential on the coal cocking property since they are oxidized readily.