CAJ | 학술논문

以1，3-丙二胺与乙酰丙酸为原料反应得二氮杂二环，然后加入缚酸剂NaOH与二氯乙酰氯一锅法反应制备了5-二氯乙酰基-6-甲基-9-氧杂-1，5-二氮杂二环[4．3．0]壬烷，采用红外光谱、氢核磁、碳核磁进行了表征，并对所合成物质进行了拆分，采用室内生物测定法研究了外消旋体及其光学异构体在土壤中豆磺隆残留时对玉米的保护效果。
이1，3-병이알여을선병산위원료반응득이담잡이배，연후가입박산제NaOH여이록을선록일과법반응제비료5-이록을선기-6-갑기-9-양잡-1，5-이담잡이배[4．3．0]임완，채용홍외광보、경핵자、탄핵자진행료표정，병대소합성물질진행료탁분，채용실내생물측정법연구료외소선체급기광학이구체재토양중두광륭잔류시대옥미적보호효과。
A novel diazabicyclo compound 5 - dichloroacetyl - 6 - methyl - 9 - oxo - 1, 5 - diazabicyclo [ 4.3.0 ] nonane was synthesized with 1, 3 -propanediamine, acetylpropionicacid and dichloroacetyl chloride. The compound was characterized by IR, ^1H NMR and ^13 C NMR. Resolution of this compound with L - ( + ) - tartaric acid was also carried out. The preliminary biological test showed that the compounds protected maize against injure by chlorimuron to some ex-tent.