广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
23期
34-35,41
,共3页
毛兰兰%袁霖%张敏%陈艳红%杨俭%刘望
毛蘭蘭%袁霖%張敏%陳豔紅%楊儉%劉望
모란란%원림%장민%진염홍%양검%류망
乙酸异戊酯%合成%磺化炭%酯化%微波辐射
乙痠異戊酯%閤成%磺化炭%酯化%微波輻射
을산이무지%합성%광화탄%지화%미파복사
isoamyl acetate%synthesis%solid sulfonic acid%esterification%microwave irradiation
在微波辐射下，用活性炭磺化制得固体磺化炭作为催化剂，由乙酸和异戊醇合成乙酸异戊酯。对乙酸与异戊醇酯化反应条件进行优化，优化条件是：酸醇摩尔比为1．8：1，反应温度为200℃，反应时间为20min，催化剂用量为实际反应的乙酸质量的8％．乙酸的酯化率达85．51％．产物经过红外光谱表征。
在微波輻射下，用活性炭磺化製得固體磺化炭作為催化劑，由乙痠和異戊醇閤成乙痠異戊酯。對乙痠與異戊醇酯化反應條件進行優化，優化條件是：痠醇摩爾比為1．8：1，反應溫度為200℃，反應時間為20min，催化劑用量為實際反應的乙痠質量的8％．乙痠的酯化率達85．51％．產物經過紅外光譜錶徵。
재미파복사하，용활성탄광화제득고체광화탄작위최화제，유을산화이무순합성을산이무지。대을산여이무순지화반응조건진행우화，우화조건시：산순마이비위1．8：1，반응온도위200℃，반응시간위20min，최화제용량위실제반응적을산질량적8％．을산적지화솔체85．51％．산물경과홍외광보표정。
Isoamyl acetate was synthesized from acetic acid and isoamyl alcohol with solid sulfonic acid sulfonated ac-tivated carbon as catalyst under microwave irradiation. The effect of factors on the yield was studied and the optimum reac-tion conditions were found. They were as follows: molar ratio of acetic acid to isoamyl alcohol was 1.8 : 1, reaction tem-perature 200 ℃, reaction time 20 min, and the dosage of the catalyst was 8% of the practical acetic acid quality. Under the conditions, the yield was 85.51%. The product was characterized by IR.
