皖西学院学报
皖西學院學報
환서학원학보
JOURNAL OF WANXI UNIVERSITY
2012年
5期
113-115
,共3页
双四硫富瓦烯衍生物%合成反应%光诱导电子转移反应
雙四硫富瓦烯衍生物%閤成反應%光誘導電子轉移反應
쌍사류부와희연생물%합성반응%광유도전자전이반응
Bis-tetrathiafulvalene Derivative synthesis reaction photoindueed electron-transfer reaction
4，5-（2′-氰乙基硫基）-6，7-二丁硫基四硫富瓦烯在甲醇钠的作用下消除一个氰乙基生成四硫富瓦烯衍生物的单钠盐，此单钠盐再与9，10-二（氯甲基）蒽反应生成新型U型双四硫富瓦烯衍生物。实验结果表明，这种新型U型双四硫富瓦烯衍生物与C60之间产生光诱导电子转移反应使其荧光显著增强。
4，5-（2′-氰乙基硫基）-6，7-二丁硫基四硫富瓦烯在甲醇鈉的作用下消除一箇氰乙基生成四硫富瓦烯衍生物的單鈉鹽，此單鈉鹽再與9，10-二（氯甲基）蒽反應生成新型U型雙四硫富瓦烯衍生物。實驗結果錶明，這種新型U型雙四硫富瓦烯衍生物與C60之間產生光誘導電子轉移反應使其熒光顯著增彊。
4，5-（2′-청을기류기）-6，7-이정류기사류부와희재갑순납적작용하소제일개청을기생성사류부와희연생물적단납염，차단납염재여9，10-이（록갑기）은반응생성신형U형쌍사류부와희연생물。실험결과표명，저충신형U형쌍사류부와희연생물여C60지간산생광유도전자전이반응사기형광현저증강。
4,5-Bis(2'-cyanoethylthio)-6,7-bis(buthylthio) teirathiafulvalene was treated with sodium methoxide to deprotect one 2-cyanoethyl group, affording tetrathiafulvalene derivative rnonothiolate. The generated monothiolate was trapped by 9, 10-his (chloromomethylene) anthracene, to yield the corresponding singly bridged type U of bis-tetrathiafulvalene derivative. The experiment results showed that it is possible to tune the intermolecular photoinduced electron-transfer process between 1240 and type U of bis-tetrathiafulvalene derivative, leading to fluorescence enhancement.
