上海涂料
上海塗料
상해도료
SHANGHAI COATINGS
2012年
11期
24-27
,共4页
水性聚氨酯分散体%稳定性%硬度%耐水性
水性聚氨酯分散體%穩定性%硬度%耐水性
수성취안지분산체%은정성%경도%내수성
waterborne polyurethane dispersion%stability%hardness%water resistance
以异佛尔酮二异氰酸酯(IPDI)、甲苯-2,4-二异氰酸酯(TDI)、聚碳酸酯二醇(L5652—2000)和聚四氢呋喃二醇(PTMG-2000)为主要原料,2,2-二羟甲基丙酸(DMPA)为亲水单体,1,4-丁二醇(BDO)和乙二胺(EA)为扩链剂,在不同条件下制备了系列水性聚氨酯分散体。通过对胶膜硬度、吸水率以及附着力等的研究,分析了分子结构及分散条件对分散体稳定性和胶膜性能的影响。
以異彿爾酮二異氰痠酯(IPDI)、甲苯-2,4-二異氰痠酯(TDI)、聚碳痠酯二醇(L5652—2000)和聚四氫呋喃二醇(PTMG-2000)為主要原料,2,2-二羥甲基丙痠(DMPA)為親水單體,1,4-丁二醇(BDO)和乙二胺(EA)為擴鏈劑,在不同條件下製備瞭繫列水性聚氨酯分散體。通過對膠膜硬度、吸水率以及附著力等的研究,分析瞭分子結構及分散條件對分散體穩定性和膠膜性能的影響。
이이불이동이이청산지(IPDI)、갑분-2,4-이이청산지(TDI)、취탄산지이순(L5652—2000)화취사경부남이순(PTMG-2000)위주요원료,2,2-이간갑기병산(DMPA)위친수단체,1,4-정이순(BDO)화을이알(EA)위확련제,재불동조건하제비료계렬수성취안지분산체。통과대효막경도、흡수솔이급부착력등적연구,분석료분자결구급분산조건대분산체은정성화효막성능적영향。
The series of waterborne polyurethane dispersion were prepared in different conditions by use of IPDI, TDI, polycarbonate diol ( L5652-2000 )and polytetrahydrofuran glycol ( PTMG-2000 )as main materials, dimethylol propionic acid as hydrophilic monomer, and 1, 4-butanediol (BDO)and ethanediamine as chain extender. The influences of molecular structure and dispersing condition on the dispersion stability and film performance were analyzed by the study of hardness, water absorption and adhesion of films.