CAJ | 학술논문

将假紫罗兰酮环化得到α、β、γ三种紫罗兰酮的混合物，再用十二羰基铁作催化剂，使混合物重排为高纯度的β-紫罗兰酮。研究表明：环化反应收率高，催化剂可套用；重排反应β-紫罗兰酮含量大于97％，对探索高含量、低污染的β-紫罗兰酮工业合成路线具有重要指导作用。
장가자라란동배화득도α、β、γ삼충자라란동적혼합물，재용십이탄기철작최화제，사혼합물중배위고순도적β-자라란동。연구표명：배화반응수솔고，최화제가투용；중배반응β-자라란동함량대우97％，대탐색고함량、저오염적β-자라란동공업합성로선구유중요지도작용。
A mixture composed of α,β, γ-ionones can be prepared from pseudoionone via cyclization, which can be further converted to high levels of pure β-ionone via rearrangement using Fe3(CO)12 as the catalyst. The new β-ionone synthesis route proposed has the following advantages, such as high yield of the cyclization reaction, recovery and reuse of the catalyst Fe3(CO)12, and high levels of pure product β-ionone(〉97 %), which is of great importance to explore a route for the synthesis of β-ionone in high purity and friendly environment.