CAJ | 학술논문

以天然植物色素提取物—茜素为原料与烯丙基氯进行Williamson醚化反应并通过两种方式在不饱和醚化产物的双键上引入巯基：（1）通入氯化氢气体加成,再以硫脲对氯化产物进行改性得到巯基改性茜素;（2）Co-Mo/γ-Al2O3催化下,通入硫化氢气体进行马氏规则的烯烃亲电加成反应得到巯基改性茜素。利用红外光谱对上述两种产物结构进行表征后,又将其配制为染发剂试验,结果表明,两种巯基改性的茜素染发效果均达到永久性染发剂标准。
이천연식물색소제취물—천소위원료여희병기록진행Williamson미화반응병통과량충방식재불포화미화산물적쌍건상인입구기：（1）통입록화경기체가성,재이류뇨대록화산물진행개성득도구기개성천소;（2）Co-Mo/γ-Al2O3최화하,통입류화경기체진행마씨규칙적희경친전가성반응득도구기개성천소。이용홍외광보대상술량충산물결구진행표정후,우장기배제위염발제시험,결과표명,량충구기개성적천소염발효과균체도영구성염발제표준。
Alizarin,a natural plant pigment extract,was used as raw materials to undergo Williamson etherification reaction and bring in sulfhydryl in the double bond of unsaturated etherification product through two ways:(1)aerate hydrogen chloride gas to perform addition reaction,then use thiourea to modify the chlorinated product to get sulfhydryl modified alizarin;(2)under the catalytic of Co-Mo/γ-Al2O3,aerate hydrogen sulfide(gas) to perform the olefin electrophilic addition reaction under Markovnikov's rule to get sulfhydryl modified alizarin.The structure of the above-mentioned two kinds of product was characterized by infrared spectrum.The results of a hair dye test showed that both the two kinds of sulfhydryl modified alizarin dye hair can reach the permanent colourants standard.