CAJ | 학술논문

对用手性模型标定手性分子R/S构型的方法进行了改良,建立起一种新手模型法,并以几类不同的化合物的R/S命名示例说明其用法。此外,作者首次提出了一个新的述语——手性元素,用它来概括手性中心、手性轴、手性面等。使用新手模型法,可以在没有分子模型的情况下,方便、快捷、准确地标定手性分子的R/S构型。
대용수성모형표정수성분자R/S구형적방법진행료개량,건립기일충신수모형법,병이궤류불동적화합물적R/S명명시례설명기용법。차외,작자수차제출료일개신적술어——수성원소,용타래개괄수성중심、수성축、수성면등。사용신수모형법,가이재몰유분자모형적정황하,방편、쾌첩、준학지표정수성분자적R/S구형。
A new hand model method for specifying R/S configuration of a chiral molecule was developed and illustrated by several examples.In addition,a new term,chiral element,was proposed for the first time,which meant a chiral center,a chiral axis or a chiral plane and so on.Using this method,one can handily,rapidly and accurately assigns R/S configuration of a chiral molecule without three-dimensional physical model.