CAJ | 학술논문

铱的氯桥双核配合物-1,5-环辛二烯氯化铱二聚体[Ir(COD)Cl]2由于具有独特的催化性质，已作为均相催化剂，广泛应用于各类有机合成反应进行重要药品和精细化工产品的制备。这些反应包括烷基化反应，氢化反应，氧化反应及环加成反应。[Ir(COD)Cl]2催化剂具有适用底物范围广、原料易得，对映选择性高的优点。本文对[Ir(COD)Cl]2催化的反应类型、应用和相关的反应机理进行介绍和总结。
의적록교쌍핵배합물-1,5-배신이희록화의이취체[Ir(COD)Cl]2유우구유독특적최화성질，이작위균상최화제，엄범응용우각류유궤합성반응진행중요약품화정세화공산품적제비。저사반응포괄완기화반응，경화반응，양화반응급배가성반응。[Ir(COD)Cl]2최화제구유괄용저물범위엄、원료역득，대영선택성고적우점。본문대[Ir(COD)Cl]2최화적반응류형、응용화상관적반응궤리진행개소화총결。
(1,5-cyclooctadiene) chloroiridium(I) dimmer ([Ir(COD)Cl]2) is a newly developed homogeneous catalyst with great catalytic activity and good selectivity, and has been widely used in a wide variety of organic reactions involved in production of some important medicine and chemical reagents. The organic reactions include alkylation, hydrogenation, oxidation and cycloaddition. Herein, the applications of [Ir(COD)Cl]2 in organic synthesis and related catalytic mechanisms are introduced and discussed.