CAJ | 학술논문

采用X射线光电子能谱仪及透射电子显微镜表征了自制微胶囊化次磷酸铝（T-AlHP）的包覆状况，并将其与三聚氰胺氰尿酸盐（MCA）复配阻燃玻璃纤维增强聚酰胺6（GFPA6）。结果表明：T-AlHP表面包覆了一层囊壁材料；w（T-AlHP）为20%时，阻燃GFPA6复合材料的阻燃性能达到UL94V-0级，与纯GFPA6相比，复合材料的最大质量损失速率下降6.64%/min；w（MCA）和w（T-AlHP）均为10%时，复合材料的拉伸强度、断裂拉伸应变及悬臂梁缺口冲击强度分别为126.35MPa，3.95%，8.82kJ/m2。
채용X사선광전자능보의급투사전자현미경표정료자제미효낭화차린산려（T-AlHP）적포복상황，병장기여삼취청알청뇨산염（MCA）복배조연파리섬유증강취선알6（GFPA6）。결과표명：T-AlHP표면포복료일층낭벽재료；w（T-AlHP）위20%시，조연GFPA6복합재료적조연성능체도UL94V-0급，여순GFPA6상비，복합재료적최대질량손실속솔하강6.64%/min；w（MCA）화w（T-AlHP）균위10%시，복합재료적랍신강도、단렬랍신응변급현비량결구충격강도분별위126.35MPa，3.95%，8.82kJ/m2。
The coated condition of self-made microencapsulated aluminum hypophosphite (T-AlHP) was characterized by X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy(TEM), and the T-AlHP and melamine cyanurate(MCA) compounding system was used in flame-retardant glass fiber reinforced polyamide 6(GFPA 6). The results show that the surface of aluminum hypophosphite is coated with wall materi-als. When the mass fraction of T-AlHP is 20%, the flame resistance of the flame-retardant GFPA 6 composites reaches level UL 94 V-0 and the maximum mass loss rate of the composites decreases by 6.64%/min in compari-son with that of the pure GFPA 6. The tensile strength, tensile strain at break and notched Izod impact strength of the composites is 126.35 MPa, 3.95% and 8.82 kJ/m2 respectively when both the T-AlHP content and MCA content are 10%.