化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
6期
1943-1951
,共9页
袁腾%陈卓%周显宏%涂伟萍%胡剑青%王锋
袁騰%陳卓%週顯宏%塗偉萍%鬍劍青%王鋒
원등%진탁%주현굉%도위평%호검청%왕봉
特殊润湿性%微纳二元粗糙结构%刺激响应%重组装%薄膜%油水分离
特殊潤濕性%微納二元粗糙結構%刺激響應%重組裝%薄膜%油水分離
특수윤습성%미납이원조조결구%자격향응%중조장%박막%유수분리
special wettability%micro-nanoscale binary rough structure%stimuli-responsive%reconfiguration%membranes%oil-water separation
综述了基于超亲水超疏油原理的网膜的研究进展及其在油水分离中的应用。首先介绍了研究的理论基础,包括构筑超亲水超疏油网膜的理论基础及膜分离原理,膜的基本性能及影响因素,液桥原理在超亲水超疏油膜中的应用以及该类膜的结构、制备的原材料和制备的基本方法。然后全面综述了刺激响应超亲水超疏油膜,超亲水及水下超疏油膜,无机结晶纳米线超亲水超疏油膜,分子刷结构超亲水超疏油膜及可用于含油乳液分离的网膜等的研究进展。最后指出了目前在该领域的研究中存在的一些问题,主要包括膜分离的基本理论,制备膜的原材料、膜通量、膜寿命及应用范围等,并对未来的发展进行了展望。
綜述瞭基于超親水超疏油原理的網膜的研究進展及其在油水分離中的應用。首先介紹瞭研究的理論基礎,包括構築超親水超疏油網膜的理論基礎及膜分離原理,膜的基本性能及影響因素,液橋原理在超親水超疏油膜中的應用以及該類膜的結構、製備的原材料和製備的基本方法。然後全麵綜述瞭刺激響應超親水超疏油膜,超親水及水下超疏油膜,無機結晶納米線超親水超疏油膜,分子刷結構超親水超疏油膜及可用于含油乳液分離的網膜等的研究進展。最後指齣瞭目前在該領域的研究中存在的一些問題,主要包括膜分離的基本理論,製備膜的原材料、膜通量、膜壽命及應用範圍等,併對未來的髮展進行瞭展望。
종술료기우초친수초소유원리적망막적연구진전급기재유수분리중적응용。수선개소료연구적이론기출,포괄구축초친수초소유망막적이론기출급막분리원리,막적기본성능급영향인소,액교원리재초친수초소유막중적응용이급해류막적결구、제비적원재료화제비적기본방법。연후전면종술료자격향응초친수초소유막,초친수급수하초소유막,무궤결정납미선초친수초소유막,분자쇄결구초친수초소유막급가용우함유유액분리적망막등적연구진전。최후지출료목전재해영역적연구중존재적일사문제,주요포괄막분리적기본이론,제비막적원재료、막통량、막수명급응용범위등,병대미래적발전진행료전망。
This paper reviews the research progress of membranes based on the principle of superhydrophilicity and superoleophobicity and its application in the oil-water separation. First, the fundamentals of the research are introduced, including those for preparing superhydrophilic and superoleophobic membranes and separation process, basic properties of membranes and influencing factors. The applications of liquid bridge principle in the superhydrophilic and superoleophobic membranes, membranes structures, general raw materials and prepared methods are also introduced. Then a comprehensive overview is given on the research progress of current common types of membranes, mainly including the stimuli-responsive superhydrophilic and superoleophobic membranes, superhydrophilic and underwater superoleophobic membranes, inorganic crystalline nanowires superhydrophilic and superoleophobic membranes, molecular brush structure superhydrophilic and superoleophobic membranes, and membranes for effective separation of oil-in-water emulsions. Finally, some problems in the current research area are advanced, including the basic theory of membrane separation, raw materials of membrane, membrane flux, membrane life, range of application, etc., and the development trends are prospected.