化工技术与开发
化工技術與開髮
화공기술여개발
TECHNOLOGY & DVELOPMENT OF CHEMICAL INDUSTRY
2013年
8期
10-13
,共4页
铝酸锶%Sr/Al%高温固相法合成%发光性能
鋁痠鍶%Sr/Al%高溫固相法閤成%髮光性能
려산송%Sr/Al%고온고상법합성%발광성능
strontium aluminates%Sr/Al%high temperature solid phase synthesis%luminescence properties
用高温固相法制备了铕镝掺杂的铝酸锶长余辉发光材料,通过改变Sr/Al使该类材料各自发紫光、蓝光、蓝绿光、绿光、黄绿光和黄光。光谱分析表明,当Sr/Al=0.4时发光强度最强,余辉时间最长,此时材料发黄绿光。随着Sr/Al的减小,材料的发射光谱峰值波长蓝移,激发光谱峰值波长先红移后蓝移。XRD分析可知,Sr/Al的改变使材料的晶形结构发生改变,从而影响了材料的发光性能。
用高溫固相法製備瞭銪鏑摻雜的鋁痠鍶長餘輝髮光材料,通過改變Sr/Al使該類材料各自髮紫光、藍光、藍綠光、綠光、黃綠光和黃光。光譜分析錶明,噹Sr/Al=0.4時髮光彊度最彊,餘輝時間最長,此時材料髮黃綠光。隨著Sr/Al的減小,材料的髮射光譜峰值波長藍移,激髮光譜峰值波長先紅移後藍移。XRD分析可知,Sr/Al的改變使材料的晶形結構髮生改變,從而影響瞭材料的髮光性能。
용고온고상법제비료유적참잡적려산송장여휘발광재료,통과개변Sr/Al사해류재료각자발자광、람광、람록광、록광、황록광화황광。광보분석표명,당Sr/Al=0.4시발광강도최강,여휘시간최장,차시재료발황록광。수착Sr/Al적감소,재료적발사광보봉치파장람이,격발광보봉치파장선홍이후람이。XRD분석가지,Sr/Al적개변사재료적정형결구발생개변,종이영향료재료적발광성능。
Europium and dysprosium co-doped strontium aluminates long persistence phosphors was synthesized by the solid phase. This kind of material could respectively emit purple, blue, blue-green, yellow-green, yellow light by means of the alteration of Sr/Al. Spectra test revealed the material had the best luminescence intensity and the longest afterflow when Sr/Al=0.4, it emited yellow-green light. Wave length of emission spectra peak shifted to shortwave with the reduction of Sr/Al. While wave length of excitation spectra peak firstly shifted to shortwave after shift to longwave. XRD showed the alteration of Sr/Al made crystal structure change, therefore, Sr/Al affected on lumi-nescence properties of this material.