CAJ | 학술논문

　　在水热条件下，过渡金属离子Cd2+与间苯二甲酸和1,10-菲罗啉配体反应制得配位聚合物[Cd(m-bdc)(phen)] n(m-bdc=间苯二甲酸根，phen=1,10-菲罗啉)。通过X射线单晶衍射、元素分析、红外、热重分析及荧光对其结构、组成和性质进行了表征。X射线单晶衍射结果表明该配合物为一维链状结构，间苯二甲酸的羧基氧原子分别采用双齿桥联和单齿桥联2种配位方式将相邻的2个Cd2+连接起来。热重（TG）曲线表明，该配合物的热分解过程均为2个阶段。结合Achar微分法和Coats-Redfern积分法，对其不同阶段的热分解反应动力学参数E、lnA进行了计算。
　　재수열조건하，과도금속리자Cd2+여간분이갑산화1,10-비라람배체반응제득배위취합물[Cd(m-bdc)(phen)] n(m-bdc=간분이갑산근，phen=1,10-비라람)。통과X사선단정연사、원소분석、홍외、열중분석급형광대기결구、조성화성질진행료표정。X사선단정연사결과표명해배합물위일유련상결구，간분이갑산적최기양원자분별채용쌍치교련화단치교련2충배위방식장상린적2개Cd2+련접기래。열중（TG）곡선표명，해배합물적열분해과정균위2개계단。결합Achar미분법화Coats-Redfern적분법，대기불동계단적열분해반응동역학삼수E、lnA진행료계산。
A coordination polymers [Cd(m-bdc)(phen)]n(m-bdc=m-phthalic acid anion,phen=1,10-Phenanthroline)was prepared by mixing ligands with corresponding transition metal ions under hydrothermal conditions. The complexe were characterized by single-crystal X-ray diffraction,elemental analysis, IR spectra, thermogravimetry (TG-DTG) analysis. The complexe blong to 1D chain structures, in which adjacent Cd2+ions were linked by m-phthalic acid anion ligands using its bidentate chelating and monodentate carboxylate groups. TG-DTG curves showed that complexe decomposed in two stages. The E and lnA were figured out by Achar differential method and Coasts-Redfem intergral method.