CAJ | 학술논문

CeF3 and CeF3:Tb3+ nanocrystals were successfully synthesized by the ultrasound assisted ionic liquid (IL) method at room temperature. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), high-resolution transmission electron micrographs (HRTEM) and photoluminescence (PL) spectra were employed to characterize the nanocrystals. The results of XRD indicated that the obtained samples crystallized well with a hexagonal phase crystal structure. SEM and TEM images demonstrated that the obtained CeF3:Tb3+ nanocrystals had a discoid shapein the presence of ultrasound and IL, whereas only granular nanoparticles were obtained by magnetic stirring. The possible formation mechanisms of the crystal growth were proposed. The PL spectra of the CeF3:Tb3+ nanodisks exhibited a strong green emission when excited at 254 nm. Furthermore, the photoluminescence intensity of CeF3:Tb3+ of the discoid particles was largely improved com-pared with that of the granular nanoparticles.