石油化工高等学校学报
石油化工高等學校學報
석유화공고등학교학보
JOURNAL OF PETROCHEMICAL UNIVERSITIES
2013年
6期
26-30
,共5页
阮艳军%秦波%秦玉才%孙兆林%庄新玲%于文广%董世伟%宋丽娟
阮豔軍%秦波%秦玉纔%孫兆林%莊新玲%于文廣%董世偉%宋麗娟
원염군%진파%진옥재%손조림%장신령%우문엄%동세위%송려연
CuY/Beta%吸附剂%吸附脱硫%硫容量%酸性
CuY/Beta%吸附劑%吸附脫硫%硫容量%痠性
CuY/Beta%흡부제%흡부탈류%류용량%산성
CuY/Beta%Adsorbent%Adsorptive desulfurization%Sulfur capacity%Acidity
采用液相离子交换法制备了CuY/Beta吸附剂,利用X射线衍射分析(XRD)、傅里叶红外变换光谱仪(FTIR)、N2吸附-脱附、吡啶吸附原位红外(Py-IR)等手段对吸附剂进行了表征。利用间歇静态法和固定床穿透曲线法相结合的手段来考察吸附剂对真实燃料油催化裂化油(FCC )以及加氢脱硫油(HDS )的脱硫性能。实验研究表明,CuY/Beta吸附剂与本实验室前期液相离子交换法制备的CuY吸附剂相比,CuY/Beta吸附剂的表面Lewis (L)酸酸量增多,但其强度减弱。通过对其吸附脱硫性能考察发现,与NaY/Beta复合分子筛和CuY吸附剂相比,CuY/Beta吸附剂对以上两种燃料油表现出更好的吸附脱硫效果。
採用液相離子交換法製備瞭CuY/Beta吸附劑,利用X射線衍射分析(XRD)、傅裏葉紅外變換光譜儀(FTIR)、N2吸附-脫附、吡啶吸附原位紅外(Py-IR)等手段對吸附劑進行瞭錶徵。利用間歇靜態法和固定床穿透麯線法相結閤的手段來攷察吸附劑對真實燃料油催化裂化油(FCC )以及加氫脫硫油(HDS )的脫硫性能。實驗研究錶明,CuY/Beta吸附劑與本實驗室前期液相離子交換法製備的CuY吸附劑相比,CuY/Beta吸附劑的錶麵Lewis (L)痠痠量增多,但其彊度減弱。通過對其吸附脫硫性能攷察髮現,與NaY/Beta複閤分子篩和CuY吸附劑相比,CuY/Beta吸附劑對以上兩種燃料油錶現齣更好的吸附脫硫效果。
채용액상리자교환법제비료CuY/Beta흡부제,이용X사선연사분석(XRD)、부리협홍외변환광보의(FTIR)、N2흡부-탈부、필정흡부원위홍외(Py-IR)등수단대흡부제진행료표정。이용간헐정태법화고정상천투곡선법상결합적수단래고찰흡부제대진실연료유최화열화유(FCC )이급가경탈류유(HDS )적탈류성능。실험연구표명,CuY/Beta흡부제여본실험실전기액상리자교환법제비적CuY흡부제상비,CuY/Beta흡부제적표면Lewis (L)산산량증다,단기강도감약。통과대기흡부탈류성능고찰발현,여NaY/Beta복합분자사화CuY흡부제상비,CuY/Beta흡부제대이상량충연료유표현출경호적흡부탈류효과。
Sample of CuY/Beta was prepared by modifying a NaY/Beta composite zeolite with a liquid ion-exchange method and characterized by means of X-ray diffraction (XRD ) , N2 adsorption and pyridine infrared spectroscopy (Py-FTIR ) . Desulfurization performance of CuY/Beta for fluid catalytic cracking (FCC) and hydrodesulfurization gasoline were evaluated by a fixed-bed and the intermittent static methods .The results show that the surface Lewis (L ) acidity quantity of CuY/Beta adsorbent increased greatly ,but its strength decreased , with respect to CuY adsorbents witch was prepared by liquid ion exchange method by our lab .CuY/Beta adsorbents for two kinds of fuel oils show greater performance of desulfurization than NaY/Beta and CuY adsorbents .