CAJ | 학술논문

目的：采用高压液相色谱-电感耦合等离子体质谱法(high pressure liquid chromatography coupled to in-ductively coupled plasma mass spectrometry, HPLC-ICP-MS)测定水产品中硼酸的含量。方法采用超声提取法对水产品进行前处理,优化蛋白沉淀剂、提取时间和流动相等条件。结果硼酸的检出限为0.015 mg/L,加标回收率为85.1%~112.1%,相对标准偏差(relative standard deviations, RSD)为6.0%~8.2%。结论本方法测定水产品中的硼酸含量准确、可靠,满足外源性硼酸的检测。
목적：채용고압액상색보-전감우합등리자체질보법(high pressure liquid chromatography coupled to in-ductively coupled plasma mass spectrometry, HPLC-ICP-MS)측정수산품중붕산적함량。방법채용초성제취법대수산품진행전처리,우화단백침정제、제취시간화류동상등조건。결과붕산적검출한위0.015 mg/L,가표회수솔위85.1%~112.1%,상대표준편차(relative standard deviations, RSD)위6.0%~8.2%。결론본방법측정수산품중적붕산함량준학、가고,만족외원성붕산적검측。
Objective To establish the method for the determination of boric acid in aquatic products by high pressure liquid chromatography coupled to inductively coupled plasma mass spectrometry (HPLC-ICP-MS). Methods The protein precipitation solution, extracting time and mobile phase were opti-mized and the ultrasonic extraction was used for extracting boric acid in aquatic products, and was compared with the content of boric acid by microwave digestion pretreatment. Results The limit of detection was 0.015 mg/L and the average recoveries ranged from 85.1%to 112.1%, with the relative standard deviations of 6.0%~8.2%. Conclusion The method is accurate and reliable, which is suitable for the determination of boric acid added in aquatic products.