粉末冶金材料科学与工程
粉末冶金材料科學與工程
분말야금재료과학여공정
POWDER METALLURGY MATERIALS SCIENCE AND ENGINEERING
2014年
2期
191-196
,共6页
兖利鹏%王爱琴%谢敬佩%王行
兗利鵬%王愛琴%謝敬珮%王行
연리붕%왕애금%사경패%왕행
真空热压烧结%热力学%界面
真空熱壓燒結%熱力學%界麵
진공열압소결%열역학%계면
vacuum hot-pressing sintering%thermodynamics%interface
利用真空热压法制备25SiCp/Al-30Si复合材料,采用SEM、TEM对SiCp、Sip与基体结合界面及微观组织进行表征,采用XRD分析材料的物相组成。从热力学、界面化学反应及界面润湿原理计算解释SiCp、Sip与基体的结合界面特征。结果表明,Sip/Al界面清晰、平直,表明该界面结合良好,SiC及Si未与基体发生反应。SiC与Al具有如下的匹配关系:[011]SiC//[011]Al(约差1°~2°),(111)SiC//(111)Al ,(022)SiC//(022)Al ,Al与SiC在{111}、(022)晶面上形成半共格相界。
利用真空熱壓法製備25SiCp/Al-30Si複閤材料,採用SEM、TEM對SiCp、Sip與基體結閤界麵及微觀組織進行錶徵,採用XRD分析材料的物相組成。從熱力學、界麵化學反應及界麵潤濕原理計算解釋SiCp、Sip與基體的結閤界麵特徵。結果錶明,Sip/Al界麵清晰、平直,錶明該界麵結閤良好,SiC及Si未與基體髮生反應。SiC與Al具有如下的匹配關繫:[011]SiC//[011]Al(約差1°~2°),(111)SiC//(111)Al ,(022)SiC//(022)Al ,Al與SiC在{111}、(022)晶麵上形成半共格相界。
이용진공열압법제비25SiCp/Al-30Si복합재료,채용SEM、TEM대SiCp、Sip여기체결합계면급미관조직진행표정,채용XRD분석재료적물상조성。종열역학、계면화학반응급계면윤습원리계산해석SiCp、Sip여기체적결합계면특정。결과표명,Sip/Al계면청석、평직,표명해계면결합량호,SiC급Si미여기체발생반응。SiC여Al구유여하적필배관계:[011]SiC//[011]Al(약차1°~2°),(111)SiC//(111)Al ,(022)SiC//(022)Al ,Al여SiC재{111}、(022)정면상형성반공격상계。
SiCp/Al-30Si composite was fabricated by vacuum hot-pressing sintering. Interfacial characteristics in the SiCp/Al-30Si composite were investigated using SEM、TEM、XRD, Which were calculated and explained by theoretical thermodynamic model, interface chemical reaction and wetting principle. The results show that the edges of SiC and Si are observed to be clean and sharp, indicating that no interfacial reactions have occurred. Three types of different orientation relationships are observed between the β-SiC and Al phase, with the SiC [011] parallel to the Al [011]、(111)SiC//(111)Al and (022)SiC//(022)Al , where a good semicoherent bonding exists between them.