纤维素科学与技术
纖維素科學與技術
섬유소과학여기술
JOURNAL OF CELLULOSE SCIENCE AND TECHNOLOGY
2012年
4期
24-28,35
,共6页
吴淑芳%杨德新%张厚民%李忠正
吳淑芳%楊德新%張厚民%李忠正
오숙방%양덕신%장후민%리충정
稻草%绿液%蒸煮%氧脱木素%硅
稻草%綠液%蒸煮%氧脫木素%硅
도초%록액%증자%양탈목소%규
rice straw%green liquor%cooking%oxygen delignification%silica
采用绿液蒸煮与氧脱木素联合制浆工艺对稻草原料绿液法制浆进行了初步探索。研究结果表明,稻草原料采用绿液蒸煮,在用碱量16%(Na2O计)、硫化度20%左右、最高温度150℃不保温的蒸煮条件下,可得到卡伯值26的浆料。该浆料继续氧脱木素,在氢氧化钠用量2%~3%、氧压0.7MPa、最高温度110℃条件下,可将卡伯值降至10左右。绿液蒸煮浆料得率可达60%以上,氧脱木素段得率约90%,联合制浆得率55%以上。绿液与氧脱木素联合制浆工艺可将麦草原料中约65%75%的硅保留在浆料中,并且浆料的强度性能与常规碱法浆相近。
採用綠液蒸煮與氧脫木素聯閤製漿工藝對稻草原料綠液法製漿進行瞭初步探索。研究結果錶明,稻草原料採用綠液蒸煮,在用堿量16%(Na2O計)、硫化度20%左右、最高溫度150℃不保溫的蒸煮條件下,可得到卡伯值26的漿料。該漿料繼續氧脫木素,在氫氧化鈉用量2%~3%、氧壓0.7MPa、最高溫度110℃條件下,可將卡伯值降至10左右。綠液蒸煮漿料得率可達60%以上,氧脫木素段得率約90%,聯閤製漿得率55%以上。綠液與氧脫木素聯閤製漿工藝可將麥草原料中約65%75%的硅保留在漿料中,併且漿料的彊度性能與常規堿法漿相近。
채용록액증자여양탈목소연합제장공예대도초원료록액법제장진행료초보탐색。연구결과표명,도초원료채용록액증자,재용감량16%(Na2O계)、류화도20%좌우、최고온도150℃불보온적증자조건하,가득도잡백치26적장료。해장료계속양탈목소,재경양화납용량2%~3%、양압0.7MPa、최고온도110℃조건하,가장잡백치강지10좌우。록액증자장료득솔가체60%이상,양탈목소단득솔약90%,연합제장득솔55%이상。록액여양탈목소연합제장공예가장맥초원료중약65%75%적규보류재장료중,병차장료적강도성능여상규감법장상근。
Pulping performance of rice straw by green liquor (GL) cooking combine with oxygen delignification was investigated. The results indicated that the pulp which Kappa number 26 were obtained under conditions of total titratable alkali of 16% (as Na20 on straw), sulfidity of 20% and highest temperature of 150℃. When the GL pulp was subject to oxygen delignification using alkali 2%-3%, the Kappa number decreased from 26 to around 10. The yields of green liquor cooking and oxygen delignification were above 60% and 90% respectively. Around 65%-73% of silica was kept in pulp and the physical properties of GL-O pulp were better than AP-AQ.