纤维素科学与技术
纖維素科學與技術
섬유소과학여기술
JOURNAL OF CELLULOSE SCIENCE AND TECHNOLOGY
2012年
4期
65-72
,共8页
纤维素%表面活性剂%离子型%非离子型
纖維素%錶麵活性劑%離子型%非離子型
섬유소%표면활성제%리자형%비리자형
cellulose%surfactant%ionic%non-ionic
纤维素基表面活性剂具有可生物降解、无污染等特性,具有广泛的应用前景。表面活性剂具有双亲结构,纤维素基表面活性剂通过各种化学改性的方法在纤维素骨架上引入亲水端和疏水端,使整个分子具有表面活性。文章综述了离子型和非离子型纤维素基表面活性剂的合成,以纤维素或其衍生物为原料,通过取代、聚合等方法引入长链烷基等作为疏水基团,离子结构或聚醚结构作为亲水基团,合成的表面活性剂表现出良好的表面性能,并具有高分子表面活性剂的特性。纤维素基表面活性剂在造纸工业中的助留剂和涂料分散剂方面有一定的应用,并有望用于白水处理和废纸脱墨工段。而进一步降低产品的成本并开发更高效、功能更多样的纤维素基表面活性剂将成为未来的研究方向。
纖維素基錶麵活性劑具有可生物降解、無汙染等特性,具有廣汎的應用前景。錶麵活性劑具有雙親結構,纖維素基錶麵活性劑通過各種化學改性的方法在纖維素骨架上引入親水耑和疏水耑,使整箇分子具有錶麵活性。文章綜述瞭離子型和非離子型纖維素基錶麵活性劑的閤成,以纖維素或其衍生物為原料,通過取代、聚閤等方法引入長鏈烷基等作為疏水基糰,離子結構或聚醚結構作為親水基糰,閤成的錶麵活性劑錶現齣良好的錶麵性能,併具有高分子錶麵活性劑的特性。纖維素基錶麵活性劑在造紙工業中的助留劑和塗料分散劑方麵有一定的應用,併有望用于白水處理和廢紙脫墨工段。而進一步降低產品的成本併開髮更高效、功能更多樣的纖維素基錶麵活性劑將成為未來的研究方嚮。
섬유소기표면활성제구유가생물강해、무오염등특성,구유엄범적응용전경。표면활성제구유쌍친결구,섬유소기표면활성제통과각충화학개성적방법재섬유소골가상인입친수단화소수단,사정개분자구유표면활성。문장종술료리자형화비리자형섬유소기표면활성제적합성,이섬유소혹기연생물위원료,통과취대、취합등방법인입장련완기등작위소수기단,리자결구혹취미결구작위친수기단,합성적표면활성제표현출량호적표면성능,병구유고분자표면활성제적특성。섬유소기표면활성제재조지공업중적조류제화도료분산제방면유일정적응용,병유망용우백수처리화폐지탈묵공단。이진일보강저산품적성본병개발경고효、공능경다양적섬유소기표면활성제장성위미래적연구방향。
The application prospects of cellulose-based surfactants are brightening for its characteristics such as biodegradability and pollution-free. The surfactant possesses amphiphilic structures. The hydrophilic side and hydrophobic side are induced on cellulose skeleton by chemical modifications to prepare the cellulose-based surfactants. A brief review is given regarding the synthesis of ionic and non-ionic cellulose-based surfactants. The long-chain alkyl group and ionic structure or polyester structures are induced into cellulose and its derivatives as hydrophobic and hydrophilic groups by substitution or polymerization. The synthetic surfactants have favorable properties such as surface activities and polymer properties. It can be used as retention aid and pigment dispersants in papermaking industry and is willing to be applied in white water treatment end and waste paper deinking end. To further reduce the cost of the product and develop more efficient and versatile cellulose-based surfactants will be the direction of future research.