CAJ | 학술논문

针对无机化学综合实验三草酸合铁（Ⅲ）酸钾合成过程中存在的问题,对[K3Fe（C2O4）3].3H2O的合成条件进行探索和优化.实验结果表明：在用热水（40℃）洗涤FeC2O4,40℃时逐滴加入H2O2后煮沸30s,利用浓缩后挂棉线的方式进行结晶等条件下,得到粒度较大的翠绿色晶体,可改善实验结果的重现性、提高产品的产率和纯度.
침대무궤화학종합실험삼초산합철（Ⅲ）산갑합성과정중존재적문제,대[K3Fe（C2O4）3].3H2O적합성조건진행탐색화우화.실험결과표명：재용열수（40℃）세조FeC2O4,40℃시축적가입H2O2후자비30s,이용농축후괘면선적방식진행결정등조건하,득도립도교대적취록색정체,가개선실험결과적중현성、제고산품적산솔화순도.
Aiming at the previous problems, it tries to optimize conditions of the formation for Potassium tris(oxalato)ferrate(lll) trihydrate. The experimental results show that, FeC2O4 washed with hot water, when the water tempreture is 40℃, H2O2 is added into the water drop by drop, then it must be boiled for 30s. After consentration, it is crystalized and bigger viridis crystals are gotten. Meanwhile, repeatability of experimental result is improved, productivity and purity of the products are enhanced.