四川理工学院学报:自然科学版
四川理工學院學報:自然科學版
사천리공학원학보:자연과학판
Journal of Sichuan University of Science & Engineering:Natural Science Editton
2012年
6期
14-17
,共4页
邸宏伟%马贵%周生学%李小玲
邸宏偉%馬貴%週生學%李小玲
저굉위%마귀%주생학%리소령
离子交换树脂%苯乙烯%共聚物%交换容量
離子交換樹脂%苯乙烯%共聚物%交換容量
리자교환수지%분을희%공취물%교환용량
Ion exchange resins%Styrene%Copolymers%Exchange capacity
以苯乙烯为聚合单体,二乙烯基苯为共聚单体,采用悬浮聚合法制备苯乙烯一二乙烯基苯共聚珠体,然后用浓硫酸磺化制得阳离子交换树脂。傅立叶变换红外光谱(FTIR)分析表明,成功制备了阳离子交换树脂。试验用NaOH标准溶液滴定浸泡过离子交换树脂的NaCl溶液的方法测定交换容量的大小为4.50mmol/g。以宁夏固原市自来水为研究对象,用制备的苯乙烯型阳离子交换树脂对其进行软化,采用EDTA(乙二胺四乙酸二钠盐)滴定法测量自来水浸泡阳离子交换树脂前后硬度的变化,结果表明,制备的离子交换树脂交换性能良好,降低了固原市自来水的硬度。
以苯乙烯為聚閤單體,二乙烯基苯為共聚單體,採用懸浮聚閤法製備苯乙烯一二乙烯基苯共聚珠體,然後用濃硫痠磺化製得暘離子交換樹脂。傅立葉變換紅外光譜(FTIR)分析錶明,成功製備瞭暘離子交換樹脂。試驗用NaOH標準溶液滴定浸泡過離子交換樹脂的NaCl溶液的方法測定交換容量的大小為4.50mmol/g。以寧夏固原市自來水為研究對象,用製備的苯乙烯型暘離子交換樹脂對其進行軟化,採用EDTA(乙二胺四乙痠二鈉鹽)滴定法測量自來水浸泡暘離子交換樹脂前後硬度的變化,結果錶明,製備的離子交換樹脂交換性能良好,降低瞭固原市自來水的硬度。
이분을희위취합단체,이을희기분위공취단체,채용현부취합법제비분을희일이을희기분공취주체,연후용농류산광화제득양리자교환수지。부립협변환홍외광보(FTIR)분석표명,성공제비료양리자교환수지。시험용NaOH표준용액적정침포과리자교환수지적NaCl용액적방법측정교환용량적대소위4.50mmol/g。이저하고원시자래수위연구대상,용제비적분을희형양리자교환수지대기진행연화,채용EDTA(을이알사을산이납염)적정법측량자래수침포양리자교환수지전후경도적변화,결과표명,제비적리자교환수지교환성능량호,강저료고원시자래수적경도。
The eopolymer beads body of the styrene and divinyl benzene is prepared by the suspension polymerization of styrene as the polymerizable monomer and divinyl benzene as a comonomer, and then is sulfonated into the cation exchange resin by the concentrated sulfuric acid. F-FIR indicated that the cation exchange resin has been made successfully. Test meth- od that a NaOH standard solution titrated the NaC1 solution in ion exchange resin is made to determinate the size of the exchange capacity, which is 4.50(mmol/g). Guyuan City tap water as the research object is softened by the prepared cation exchange resin of styrene-type. EDTA ( ethylenediamine tetraacetic acid disodium salt) titration method is used to measure the tap water change in hardness before and after cation exchange resin is soaked. The results showed that the prepared ion- exchange resin have a good exchange performance and greatly reduced hardness of Guyuan City tap water.