化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
8期
3250-3254
,共5页
潘彬%孙丹%刘伟凤%叶遥立%郭剑%成少安
潘彬%孫丹%劉偉鳳%葉遙立%郭劍%成少安
반빈%손단%류위봉%협요립%곽검%성소안
微生物燃料电池%碳纤维材料%阳极结构%生物量
微生物燃料電池%碳纖維材料%暘極結構%生物量
미생물연료전지%탄섬유재료%양겁결구%생물량
microbial fuel cells%carbon fiber%anode structure%biomass
微生物燃料电池(MFCs)阳极性能受生物膜的影响,而生物膜则直接与阳极表面积有关。以不同长度和数量的碳纤维丝作为阳极,研究了阳极构造和表面积对MFC输出功率的影响。当阳极为单根长度为1 cm碳纤维丝时,MFC产生的最大功率密度最高,为10.50 W·m-2,随着碳纤维丝长度逐渐增加(2~14 cm),MFC产生的最大功率显著下降。以多根的长度为2 cm碳纤维丝构成阳极时,MFC的功率与根数(1~4根)呈正比,当采用4根2 cm纤维丝时,MFC的最大功率密度为2.92 W·m-2,该数值为单根8 cm碳纤维丝的2.78倍。观察碳纤维丝长度方向上的生物膜的分布表明:受碳纤维欧姆电阻的影响,在碳纤维丝电流引出端附近的生物量明显大于碳纤维其他地方,这说明:增加纤维丝长度虽可提高阳极的表面积,但并不能提高阳极的产电性能。
微生物燃料電池(MFCs)暘極性能受生物膜的影響,而生物膜則直接與暘極錶麵積有關。以不同長度和數量的碳纖維絲作為暘極,研究瞭暘極構造和錶麵積對MFC輸齣功率的影響。噹暘極為單根長度為1 cm碳纖維絲時,MFC產生的最大功率密度最高,為10.50 W·m-2,隨著碳纖維絲長度逐漸增加(2~14 cm),MFC產生的最大功率顯著下降。以多根的長度為2 cm碳纖維絲構成暘極時,MFC的功率與根數(1~4根)呈正比,噹採用4根2 cm纖維絲時,MFC的最大功率密度為2.92 W·m-2,該數值為單根8 cm碳纖維絲的2.78倍。觀察碳纖維絲長度方嚮上的生物膜的分佈錶明:受碳纖維歐姆電阻的影響,在碳纖維絲電流引齣耑附近的生物量明顯大于碳纖維其他地方,這說明:增加纖維絲長度雖可提高暘極的錶麵積,但併不能提高暘極的產電性能。
미생물연료전지(MFCs)양겁성능수생물막적영향,이생물막칙직접여양겁표면적유관。이불동장도화수량적탄섬유사작위양겁,연구료양겁구조화표면적대MFC수출공솔적영향。당양겁위단근장도위1 cm탄섬유사시,MFC산생적최대공솔밀도최고,위10.50 W·m-2,수착탄섬유사장도축점증가(2~14 cm),MFC산생적최대공솔현저하강。이다근적장도위2 cm탄섬유사구성양겁시,MFC적공솔여근수(1~4근)정정비,당채용4근2 cm섬유사시,MFC적최대공솔밀도위2.92 W·m-2,해수치위단근8 cm탄섬유사적2.78배。관찰탄섬유사장도방향상적생물막적분포표명:수탄섬유구모전조적영향,재탄섬유사전류인출단부근적생물량명현대우탄섬유기타지방,저설명:증가섬유사장도수가제고양겁적표면적,단병불능제고양겁적산전성능。
Biofilm on anode can influence anode’s performance in microbial fuel cells(MFCs). Biofilm growth is influenced by anode surface area. The effect of anode structure on the maximum power output of MFC was investigated by changing lengths or numbers of carbon fibers as anode. For the length effect of carbon fiber anode, the highest maximum power density 10.50 W·m-2 is appeared at 1 cm-length. The maximum power density decreases sharply as the carbon fiber length further increase. When the anodes are constructed with different numbers of 2 cm-length of carbon fibers, the maximum power is proportional to amount of carbon fiber(s) (1-4 carbon fiber(s)). The maximum power for the anode with 4 pieces of 2 cm-length carbon fiber is 2.92 W·m-2, which is 2.78 times that generated with a single carbon fiber with the length of 8 cm. The biofilm on the carbon fibers surface could be observed by optical microscopy. The biofilm is much thicker at the place near current leading-out terminal than that at other parts of carbon fiber due to the resistance of the carbon fiber. These results indicate that increase of carbon fiber length can enlarge anode surface area, but can not significantly improve performance of anode.