化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
12期
3008-3014
,共7页
张克舫%刘中良%王远亚%李艳霞
張剋舫%劉中良%王遠亞%李豔霞
장극방%류중량%왕원아%리염하
化学吸收法%二氧化碳%捕集%解吸能耗%分析计算
化學吸收法%二氧化碳%捕集%解吸能耗%分析計算
화학흡수법%이양화탄%포집%해흡능모%분석계산
chemical absorption method%carbon dioxide%capture%desorption energy consumption%analysis and calculation
推导出了化学吸收法CO2捕集工艺解吸总能耗的准确计算公式,根据年产量100万吨CO2的捕集工艺流程的节点参数,分析计算了解吸能耗中各项能耗的大小,并与 Leites、晏水平、王海波等能耗估算公式结果进行了对比。分析表明,本文推导的能耗计算公式适用于设计后或运行时的能耗计算,在捕集工艺设计前可采用Leites、晏水平、王海波等公式估算解吸能耗。其中晏水平公式考虑了循环倍率,因此能耗估算公式的适用性强,循环倍率和比热容取值偏差不大时,估算精度较高。通过对推导出的解吸能耗公式的分析,即使吸收剂质量浓度、溶液的再生度、贫富液换热器的性能一定,仍能进一步降低解吸总能耗,并提出了进一步降低解吸总能耗的有效措施。
推導齣瞭化學吸收法CO2捕集工藝解吸總能耗的準確計算公式,根據年產量100萬噸CO2的捕集工藝流程的節點參數,分析計算瞭解吸能耗中各項能耗的大小,併與 Leites、晏水平、王海波等能耗估算公式結果進行瞭對比。分析錶明,本文推導的能耗計算公式適用于設計後或運行時的能耗計算,在捕集工藝設計前可採用Leites、晏水平、王海波等公式估算解吸能耗。其中晏水平公式攷慮瞭循環倍率,因此能耗估算公式的適用性彊,循環倍率和比熱容取值偏差不大時,估算精度較高。通過對推導齣的解吸能耗公式的分析,即使吸收劑質量濃度、溶液的再生度、貧富液換熱器的性能一定,仍能進一步降低解吸總能耗,併提齣瞭進一步降低解吸總能耗的有效措施。
추도출료화학흡수법CO2포집공예해흡총능모적준학계산공식,근거년산량100만둔CO2적포집공예류정적절점삼수,분석계산료해흡능모중각항능모적대소,병여 Leites、안수평、왕해파등능모고산공식결과진행료대비。분석표명,본문추도적능모계산공식괄용우설계후혹운행시적능모계산,재포집공예설계전가채용Leites、안수평、왕해파등공식고산해흡능모。기중안수평공식고필료순배배솔,인차능모고산공식적괄용성강,순배배솔화비열용취치편차불대시,고산정도교고。통과대추도출적해흡능모공식적분석,즉사흡수제질량농도、용액적재생도、빈부액환열기적성능일정,잉능진일보강저해흡총능모,병제출료진일보강저해흡총능모적유효조시。
A generalized calculation formula for the desorption energy consumption was derived and described in detail based on the mass conservation,the energy conservation and the desorption process analysis. Based on the node parameters of the 1 Mt/a CO2 capture capacity,the energy consumptions of the desorption process were analyzed and calculated with the results calculated from equations given by Leites,Yan Shuiping and Wang Haibo. The derived formula in this paper was suitable for energy consumption calculations after process design and at run time. The equations given by Leites,Yan Shuiping and Wang Haibo can be used to estimate the desorption energy consumption before the design for the capture process. If the values of the circulation ratio and the specific heat capacity were accurate,the equation given by Yan Shuiping was practical and accurate. Finally,corresponding measures were presented to reduce the desorption energy consumption according to the calculation formula,even though the absorbent concentration,the regeneration degree of the enriched absorbent and the heat exchanger performance were fixed.