CAJ | 학술논문

通过F-T合成生产液体燃料是转化利用煤、天然气和生物质并解决石油短缺问题的一种有效途径，采用轻度加氢裂解F-T合成过程中产生的高沸点蜡油可以生产清洁优质的柴油和喷气燃料。本文对近年F-T合成蜡油加氢裂解的研究进展进行了综述，简要介绍了F-T合成蜡油加氢裂解的反应机理，讨论了集总动力学和单事件动力学在F-T合成蜡油加氢裂解中的应用情况，对F-T合成蜡加氢裂解催化剂体系以及反应影响因素进行了分析。反应精馏工艺可以提高F-T合成蜡加氢裂解高转化率时柴油的选择性，除了开发更高效的催化剂以外，F-T合成蜡油加氢裂解反应精馏的研究与应用将具有重大前景。
통과F-T합성생산액체연료시전화이용매、천연기화생물질병해결석유단결문제적일충유효도경，채용경도가경렬해F-T합성과정중산생적고비점사유가이생산청길우질적시유화분기연료。본문대근년F-T합성사유가경렬해적연구진전진행료종술，간요개소료F-T합성사유가경렬해적반응궤리，토론료집총동역학화단사건동역학재F-T합성사유가경렬해중적응용정황，대F-T합성사가경렬해최화제체계이급반응영향인소진행료분석。반응정류공예가이제고F-T합성사가경렬해고전화솔시시유적선택성，제료개발경고효적최화제이외，F-T합성사유가경렬해반응정류적연구여응용장구유중대전경。
Fischer-Tropsch synthesis is an important process to convert coal,natural gas and biomass into liquid fuel,and is a promising process for resolving the shortage of petroleum. Mild hydrocracking is an effective route to upgrade the heavy waxy hydrocarbons derived from Fischer-Tropsch synthesis reaction into high value fuels,such as clean,high-quality diesel and jet fuel. In this paper,the recent advances in hydrocracking Fischer-Tropsch wax are reviewed. The mechanism of hydrocracking Fischer-Tropsch wax is introduced,the modeling of hydrocracking Fischer-Tropsch wax through lump and single-event kinetics is discussed,and the catalytic system as well as influence factors of the reaction are analyzed. Reactive distillation process can improve the selectivity of hydrocracking Fischer-Tropsch wax at a high conversion rate toward diesel. Apart from research and development of more effective catalysts,the study and application of Fischer-Tropsch wax hydrocracking reactive distillation process will have significant prospect.