光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2013年
12期
3396-3401
,共6页
殷淑华%高博%李强%周怀东%王健康%黄勇
慇淑華%高博%李彊%週懷東%王健康%黃勇
은숙화%고박%리강%주부동%왕건강%황용
非常规监测微量元素%道路尘土%地积累指数%污染源%石河子
非常規鑑測微量元素%道路塵土%地積纍指數%汙染源%石河子
비상규감측미량원소%도로진토%지적루지수%오염원%석하자
Seldom monitored trace elements%Roadside dusts%Geoaccumulation index%Pollution sources%Shihezi city
采集了石河子城区32个站点的道路尘土样本,测定了样品中10种非常规监测微量元素(B ,Be , Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl ,V)的含量。并采用地积累指数法、元素相关性分析和主成分分析法对尘土中的微量元素污染程度和来源进行了分析。结果表明:道路尘土中微量B ,Be ,Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl和V的平均含量分别为41.11,1.68,0.52,13.58,36.26,24.91,3.37,3.64,0.42,72.66 mg · kg -1。其中, Co ,Li和Tl的平均含量均低于新疆土壤元素背景值,B ,Be和V的平均含量和新疆土壤元素背景值相似, Bi ,Ga ,Sb和Sn的平均含量高于新疆和世界土壤元素背景值。地积累指数计算结果表明:B ,Be ,Co ,Ga , Li ,Tl和V污染级数为0,说明无污染,而Sb ,Bi和Sn污染较为严重(污染等级分别为2,1,1)。元素相关性分析和主成分分析多元统计方法计算结果表明,Bi ,Co ,Sb和Tl主要是人为来源,B ,Be ,Li和V主要是自然来源,而Ga和Sn可能受自然因素和人为因素的共同影响。
採集瞭石河子城區32箇站點的道路塵土樣本,測定瞭樣品中10種非常規鑑測微量元素(B ,Be , Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl ,V)的含量。併採用地積纍指數法、元素相關性分析和主成分分析法對塵土中的微量元素汙染程度和來源進行瞭分析。結果錶明:道路塵土中微量B ,Be ,Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl和V的平均含量分彆為41.11,1.68,0.52,13.58,36.26,24.91,3.37,3.64,0.42,72.66 mg · kg -1。其中, Co ,Li和Tl的平均含量均低于新疆土壤元素揹景值,B ,Be和V的平均含量和新疆土壤元素揹景值相似, Bi ,Ga ,Sb和Sn的平均含量高于新疆和世界土壤元素揹景值。地積纍指數計算結果錶明:B ,Be ,Co ,Ga , Li ,Tl和V汙染級數為0,說明無汙染,而Sb ,Bi和Sn汙染較為嚴重(汙染等級分彆為2,1,1)。元素相關性分析和主成分分析多元統計方法計算結果錶明,Bi ,Co ,Sb和Tl主要是人為來源,B ,Be ,Li和V主要是自然來源,而Ga和Sn可能受自然因素和人為因素的共同影響。
채집료석하자성구32개참점적도로진토양본,측정료양품중10충비상규감측미량원소(B ,Be , Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl ,V)적함량。병채용지적루지수법、원소상관성분석화주성분분석법대진토중적미량원소오염정도화래원진행료분석。결과표명:도로진토중미량B ,Be ,Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl화V적평균함량분별위41.11,1.68,0.52,13.58,36.26,24.91,3.37,3.64,0.42,72.66 mg · kg -1。기중, Co ,Li화Tl적평균함량균저우신강토양원소배경치,B ,Be화V적평균함량화신강토양원소배경치상사, Bi ,Ga ,Sb화Sn적평균함량고우신강화세계토양원소배경치。지적루지수계산결과표명:B ,Be ,Co ,Ga , Li ,Tl화V오염급수위0,설명무오염,이Sb ,Bi화Sn오염교위엄중(오염등급분별위2,1,1)。원소상관성분석화주성분분석다원통계방법계산결과표명,Bi ,Co ,Sb화Tl주요시인위래원,B ,Be ,Li화V주요시자연래원,이Ga화Sn가능수자연인소화인위인소적공동영향。
Seldom monitored trace element concentrations in road dusts colleted from Shihezi City were studied .A total of 32 sampling stations were selected .The concentration of 10 seldom monitored trace elements (B ,Be ,Bi ,Co ,Ga ,Li ,Sb ,Sn ,Tl , V) were determined .Their pollution degree and source identification were analyzed by using Geoaccumulation Index ,correlation coefficient and principal factor analysis .The results indicated that the mean concentrations of Li ,Be ,B ,V ,Co ,Ga ,Sn ,Sb ,Tl and Bi were 24.91 ,1.68 ,41.11 ,72.66 ,13.58 ,36.26 ,3.64 ,3.37 ,0.42 and 0.52 mg · kg -1 ,respectively .The mean con-centrations of Li ,Tl ,Co ,Be ,B ,and V were lower than or similar to the soil background values of Xinjiang province .Howev-er ,the mean concentrations of Ga ,Sn ,Sb and Bi were higher than the background values of Xijiang province and world soil . The results of Geoaccumulation Index indicated that the pollution degrees of Li ,Be ,B ,V ,Co ,Ga and Tl were zero ,and be-longed to the category of non-pollution .However the pollution of Sb ,Bi and Sn were considerably serious ,and their pollution grades were 2 ,1 and 1 respectively .The source of SMTEs in road dusts of Shihezi City was identified by multivariate statistics (principal component analysis and correlation analysis ) .The results showed that Sb ,Co ,Tl and Bi mainly originated from hu-man activities ,Li ,Be ,B ,V represented natural sources ,while Sn and Ga have the mixed sources of nature and human activi-ties .