光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2013年
12期
3308-3311
,共4页
李仰军%焦宁%王瑞军%雷树峰%王高
李仰軍%焦寧%王瑞軍%雷樹峰%王高
리앙군%초저%왕서군%뢰수봉%왕고
光谱分析%弹光调制%双折射%甲醛
光譜分析%彈光調製%雙摺射%甲醛
광보분석%탄광조제%쌍절사%갑철
Spectrum analysis%Photo-elastic modulation%Birefringence%Formaldehyde
由于室内甲醛超标造成的环境污染日益增多,为了快速、准确地对室内空气中甲醛气体的浓度进行定量分析,设计了基于弹光调制的甲醛气体浓度检测系统,由红外光源、滤光片、弹光调制器、红外探测器等构成,由弹光调制器控制弹光晶体折射率周期性变化,折射率造成的光程变化提供了反演光谱分布函数的光程差。通过HITRAN光谱数据库推导了系统可获得的光程差函数。实验采用红外光源与窄带滤波片结合,中心波长透过率在90%以上,采用硒化锌晶体作为弹光调制晶体,系统的驱动频率为100 kHz。对三种不同环境下不同位置分别采集十组样气进行分析,同时采用标准光谱仪和本系统进行甲醛气体浓度检测。实验结果显示,当甲醛气体浓度较高时,系统性能良好;当甲醛气体浓度较低时,系统信噪比下降,检测精度略有降低,但仍能满足设计要求。
由于室內甲醛超標造成的環境汙染日益增多,為瞭快速、準確地對室內空氣中甲醛氣體的濃度進行定量分析,設計瞭基于彈光調製的甲醛氣體濃度檢測繫統,由紅外光源、濾光片、彈光調製器、紅外探測器等構成,由彈光調製器控製彈光晶體摺射率週期性變化,摺射率造成的光程變化提供瞭反縯光譜分佈函數的光程差。通過HITRAN光譜數據庫推導瞭繫統可穫得的光程差函數。實驗採用紅外光源與窄帶濾波片結閤,中心波長透過率在90%以上,採用硒化鋅晶體作為彈光調製晶體,繫統的驅動頻率為100 kHz。對三種不同環境下不同位置分彆採集十組樣氣進行分析,同時採用標準光譜儀和本繫統進行甲醛氣體濃度檢測。實驗結果顯示,噹甲醛氣體濃度較高時,繫統性能良好;噹甲醛氣體濃度較低時,繫統信譟比下降,檢測精度略有降低,但仍能滿足設計要求。
유우실내갑철초표조성적배경오염일익증다,위료쾌속、준학지대실내공기중갑철기체적농도진행정량분석,설계료기우탄광조제적갑철기체농도검측계통,유홍외광원、려광편、탄광조제기、홍외탐측기등구성,유탄광조제기공제탄광정체절사솔주기성변화,절사솔조성적광정변화제공료반연광보분포함수적광정차。통과HITRAN광보수거고추도료계통가획득적광정차함수。실험채용홍외광원여착대려파편결합,중심파장투과솔재90%이상,채용서화자정체작위탄광조제정체,계통적구동빈솔위100 kHz。대삼충불동배경하불동위치분별채집십조양기진행분석,동시채용표준광보의화본계통진행갑철기체농도검측。실험결과현시,당갑철기체농도교고시,계통성능량호;당갑철기체농도교저시,계통신조비하강,검측정도략유강저,단잉능만족설계요구。
There is a growing number of environmental pollution caused by excessive indoor formaldehyde ,and in order to quick-ly and accurately quantify the concentration of formaldehyde gas in indoor air ,a system for detecting the concentration of formal-dehyde gas based on photo-elastic modulation was designed .It consists of the infrared light source ,filters ,elastic light modula-tor ,and infrared detectors ,and photo-elastic crystal refractive index of cyclical changes was controlled by elastic light modula-tor .Refractive index caused by the changes in the optical path provided a spectrum distribution function of the optical path differ-ence .Optical path difference function of the system was derived through the HITRAN spectral database .Experiments were car-ried out using infrared light source combined with narrow band filters ,and the transmittance of the center wavelength was more than 90% .Photo-elastic crystal is ZnSe crystal as photo-elastic light modulator ,and the drive frequency of the system is 100 kHz .For three different environments at different locations ,10 groups of sample gas were collected for analysis ,and the con-centration of formaldehyde gas was detected using standard spectrometer and the system for comparing the test data .Experimen-tal results show that when the concentration of formaldehyde gas is high ,the system performance is good ;When the concentra-tion of formaldehyde gas is low ,the signal-to-noise ratio of the system is decreased ,and the detection accuracy is slightly re-duced ,but it still meets the design requirements .