化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
7期
1584-1590,1603
,共8页
类水滑石%层层自组装技术%薄膜材料
類水滑石%層層自組裝技術%薄膜材料
류수활석%층층자조장기술%박막재료
layered double hydroxides%layer-by-layer self-assembly method%film material
类水滑石(layered double hydroxides,LDHs)具有各向异性的结构特征、特殊的理化特性及多功能性,在材料科学领域得到广泛应用。本文围绕近年来 LDHs 基薄膜材料的研究进展,系统概括了层层自组装技术(layer-by-layer self-assembly,LBL 技术)制备的 LDHs 基新型薄膜材料的基础作用力(如静电吸附作用、氢键作用等),阐述了 LDHs 与无机分子(如蒙脱石、二氧化锰、石墨烯等)、有机分子(如聚乙烯醇、荧光染料、聚苯乙烯磺酸盐等)等组装制备的特性薄膜材料,并总结了其在光、电、催化、生物无机材料等方面的应用。指出伴随着制备方法、化学组成及成膜作用力等方面基础研究的深入以及对 LBL 技术的功能化、实用化研究的日臻成熟,以 LBL 技术构筑的 LDHs 基薄膜材料必将对材料、化学、生物等科技领域产生深远的影响。
類水滑石(layered double hydroxides,LDHs)具有各嚮異性的結構特徵、特殊的理化特性及多功能性,在材料科學領域得到廣汎應用。本文圍繞近年來 LDHs 基薄膜材料的研究進展,繫統概括瞭層層自組裝技術(layer-by-layer self-assembly,LBL 技術)製備的 LDHs 基新型薄膜材料的基礎作用力(如靜電吸附作用、氫鍵作用等),闡述瞭 LDHs 與無機分子(如矇脫石、二氧化錳、石墨烯等)、有機分子(如聚乙烯醇、熒光染料、聚苯乙烯磺痠鹽等)等組裝製備的特性薄膜材料,併總結瞭其在光、電、催化、生物無機材料等方麵的應用。指齣伴隨著製備方法、化學組成及成膜作用力等方麵基礎研究的深入以及對 LBL 技術的功能化、實用化研究的日臻成熟,以 LBL 技術構築的 LDHs 基薄膜材料必將對材料、化學、生物等科技領域產生深遠的影響。
류수활석(layered double hydroxides,LDHs)구유각향이성적결구특정、특수적이화특성급다공능성,재재료과학영역득도엄범응용。본문위요근년래 LDHs 기박막재료적연구진전,계통개괄료층층자조장기술(layer-by-layer self-assembly,LBL 기술)제비적 LDHs 기신형박막재료적기출작용력(여정전흡부작용、경건작용등),천술료 LDHs 여무궤분자(여몽탈석、이양화맹、석묵희등)、유궤분자(여취을희순、형광염료、취분을희광산염등)등조장제비적특성박막재료,병총결료기재광、전、최화、생물무궤재료등방면적응용。지출반수착제비방법、화학조성급성막작용력등방면기출연구적심입이급대 LBL 기술적공능화、실용화연구적일진성숙,이 LBL 기술구축적 LDHs 기박막재료필장대재료、화학、생물등과기영역산생심원적영향。
Due to its structural anisotropy , novel physical and chemical properties , and multifunctionality,layered double hydroxides (LDHs) has been widely used in the field of materials science. Focusing on the study in recent years on thin-film materials based on LDHs,the paper is aimed to summarize the basic forces of the thin-film material produced by layer-by-layer self-assembly method (such as electrostatic adsorption,hydrogen bonding,etc.),and to expound LDHs assembled with inorganic molecules (montmorillonite,manganese dioxide,graphene,etc.),organic molecules (such as poly (vinyl alcohol),fluorescent dyes,polystyrene sulfonate,etc.) and so on. Applications of thin film on light,electricity,catalysis,biology-inorganic materials are also discussed in detail. With the basic research on preparation,chemical composition and the main forces for assembling in depth, as well as the functionality and practical application of the LBL technology being mature,the thin-film materials based on LDHs via LBL method have a profound impact in many fields including materials, chemical,biological,and other high-tech areas.