世界科学技术-中医药现代化
世界科學技術-中醫藥現代化
세계과학기술-중의약현대화
WORLD SCIENCE AND TECHNOLOGY-MODERNIZATION OF TRADITIONAL CHINESE MEDICINE
2013年
3期
527-530
,共4页
贺锐锐%谭鹏%韩静%林宏英%陈鑫%刘永刚%张燕玲
賀銳銳%譚鵬%韓靜%林宏英%陳鑫%劉永剛%張燕玲
하예예%담붕%한정%림굉영%진흠%류영강%장연령
五味子乙素%ESI-MS/MS%裂解途径
五味子乙素%ESI-MS/MS%裂解途徑
오미자을소%ESI-MS/MS%렬해도경
Schisandrin B%ESI-MS/MS%fragmentation pathways
目的:基于Discovery Studio软件研究五味子乙素的质谱裂解机制。方法:在正离子模式,用线性离子阱质谱得到五味子乙素的质谱图。结果:通过Discovery Studio解析五味子乙素多级质谱碎片,主要发生环的开裂,H2O,-CH3和-OCH3等自由基丢失。结论:本研究丰富五味子乙素的质谱裂解机制,为木脂素类成分的结构鉴定研究提供依据。
目的:基于Discovery Studio軟件研究五味子乙素的質譜裂解機製。方法:在正離子模式,用線性離子阱質譜得到五味子乙素的質譜圖。結果:通過Discovery Studio解析五味子乙素多級質譜碎片,主要髮生環的開裂,H2O,-CH3和-OCH3等自由基丟失。結論:本研究豐富五味子乙素的質譜裂解機製,為木脂素類成分的結構鑒定研究提供依據。
목적:기우Discovery Studio연건연구오미자을소적질보렬해궤제。방법:재정리자모식,용선성리자정질보득도오미자을소적질보도。결과:통과Discovery Studio해석오미자을소다급질보쇄편,주요발생배적개렬,H2O,-CH3화-OCH3등자유기주실。결론:본연구봉부오미자을소적질보렬해궤제,위목지소류성분적결구감정연구제공의거。
This study was aimed to find the fragmentation pathways of Schisandrin B using the Discovery Studio by electrospray ionization mass spectrometry (ESI-MSn). The first and multi-stage mass spectrum diagrams were obtained. The results showed that mass spectrometry fragments of Schisandrin B was analyzed under the positive mode, the cracking rings are mainly occurred, and free radicals such as H2O, -CH3 and -OCH3 were lost. It was concluded that this study enriched the mass spectral decomposition, and provided basis for the study on chemical constituents of lignan compounds.