兵器材料科学与工程
兵器材料科學與工程
병기재료과학여공정
Ordnance Material Science and Engineering
2013年
3期
41-44
,共4页
染料敏化太阳能电池%对电极%石墨%碳黑
染料敏化太暘能電池%對電極%石墨%碳黑
염료민화태양능전지%대전겁%석묵%탄흑
dye sensitized solar cells%counter electrode%graphite%carbon black
为研究碳黑掺入量对TiO2/石墨共混薄膜的电学与电化学性能的影响，采用场发射扫描电子显微镜、四探针电阻率测试仪、电化学交流阻抗图谱以及太阳能电池综合测试仪对碳薄膜的表面形貌、电学、电化学性质以及电池的光电性能进行表征测试。结果表明：碳黑的加入使碳对电极的方块电阻降低了35%；当掺入质量分数为5%的碳黑时，碳对电极的界面电荷传输电阻及光电性能达到最佳，其光电转换效率可达到Pt对电极的74%。
為研究碳黑摻入量對TiO2/石墨共混薄膜的電學與電化學性能的影響，採用場髮射掃描電子顯微鏡、四探針電阻率測試儀、電化學交流阻抗圖譜以及太暘能電池綜閤測試儀對碳薄膜的錶麵形貌、電學、電化學性質以及電池的光電性能進行錶徵測試。結果錶明：碳黑的加入使碳對電極的方塊電阻降低瞭35%；噹摻入質量分數為5%的碳黑時，碳對電極的界麵電荷傳輸電阻及光電性能達到最佳，其光電轉換效率可達到Pt對電極的74%。
위연구탄흑참입량대TiO2/석묵공혼박막적전학여전화학성능적영향，채용장발사소묘전자현미경、사탐침전조솔측시의、전화학교류조항도보이급태양능전지종합측시의대탄박막적표면형모、전학、전화학성질이급전지적광전성능진행표정측시。결과표명：탄흑적가입사탄대전겁적방괴전조강저료35%；당참입질량분수위5%적탄흑시，탄대전겁적계면전하전수전조급광전성능체도최가，기광전전환효솔가체도Pt대전겁적74%。
The influence of mixing amount of carbon black on electrical and electrochemical properties of TiO2/graphite blend film was studied. Morphologies,electrical properties and electrochemical properties of electrodes were characterized by scanning electron microscopy,four probe method and electrochemical impedance spectroscopy,respectively. Photovoltaic performance of the cells was examined. It is found that the sheet resistance of carbon counter electrode decreases by 35% with incorporation of carbon black. When carbon black content is 5%(mass fraction),charge transfer resistance and photovoltaic performance reach the optimum. Photoelectric conversion efficiency reaches 74% of the cells with Pt counter electrode.
