CAJ | 학술논문

以邻甲酚缩水甘油醚和丙烯酸为主要原料，三苯基膦为催化剂、4-甲氧基酚为阻聚剂，合成了一种低黏度的活性稀释剂邻甲酚缩水甘油醚丙烯酸酯。研究了反应温度、阻聚剂、催化剂用量这些因素对反应的影响，结果表明较好的合成反应条件是：反应温度为100℃～110℃、三苯基膦质量分数为0．80％、4-甲氧基酚质量分数为0．30％～0．40％。同时，把邻甲酚缩水甘油醚丙烯酸酯作为稀释剂加入到双酚 A型环氧丙烯酸酯中配制成紫外光固化涂料，对涂膜进行了拉伸、硬度、柔韧性等测试，结果表明此预聚物配成的涂料具有较好的力学性能。
이린갑분축수감유미화병희산위주요원료，삼분기련위최화제、4-갑양기분위조취제，합성료일충저점도적활성희석제린갑분축수감유미병희산지。연구료반응온도、조취제、최화제용량저사인소대반응적영향，결과표명교호적합성반응조건시：반응온도위100℃～110℃、삼분기련질량분수위0．80％、4-갑양기분질량분수위0．30％～0．40％。동시，파린갑분축수감유미병희산지작위희석제가입도쌍분 A형배양병희산지중배제성자외광고화도료，대도막진행료랍신、경도、유인성등측시，결과표명차예취물배성적도료구유교호적역학성능。
The low viscosity O-cresol glycidyl ether acrylate was synthesized with O-cresol glycidyl ether and acrylic acid as the main materials,with triphenyl phosphine as the catalyst,and 4-methoxy phenol as the inhibitor.The effects of temperature,the dosage of catalyst and inhibitor on the process were also in-vestigated.Experimental results showed that the optimum reaction temperature was 110~110 ℃,the cat-alyst mass fraction was 0.80% and the inhibitor mass fraction was 0.30%~0.40%.Meanwhile,the UV-cured coating was prepared with adding O-cresol glycidyl ether acrylate to bisphenol A type epoxy diacry-late,The tensile test,hardness test and flexibility test were performed on the UV-cured films.The results showed that the coating had good mechanical properties.