CAJ | 학술논문

　　文章用Adler法将吡咯和羧基苯甲醛反应合成了5,10,15,20-四(4-羧基苯基)卟啉(TCPP)，用反复调pH法得到了较纯净的TCPP，解决了TCPP分离纯化困难的问题；并合成了其Zn(II)和Co(II)的配合物，并利用紫外，1H-NMR荧光，红外和EPR对其光谱进行了研究。
　　문장용Adler법장필각화최기분갑철반응합성료5,10,15,20-사(4-최기분기)계람(TCPP)，용반복조pH법득도료교순정적TCPP，해결료TCPP분리순화곤난적문제；병합성료기Zn(II)화Co(II)적배합물，병이용자외，1H-NMR형광，홍외화EPR대기광보진행료연구。
In the paper, meso-tetra(4-carboxyphenyl) porphyrin (TCPP) was synthesized according to the Adler method with pyrrole and carboxybenzaldehyde. In order to solve the separation and purification difficult problem of TCPP, slao repeated a new way to obtain a relatively pure TCPP by adjusting pH. And their related zinc (II) and 1cobalt (II) complexes are also synthesized,These compounds have been characterized by UV-Vis, 1H-NMR,FL, IR and EPR spectral determinations.