广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2013年
9期
10-11
,共2页
李冠君%贾春梅%冯潇%王婧%袁文兵
李冠君%賈春梅%馮瀟%王婧%袁文兵
리관군%가춘매%풍소%왕청%원문병
5-氨基间苯二甲酸%机械化学%液体辅助球磨
5-氨基間苯二甲痠%機械化學%液體輔助毬磨
5-안기간분이갑산%궤계화학%액체보조구마
mechanochemistry%metal organic frameworks%5-Aminoisophthalic acid
采用振荡式球磨机作为机械能发生装置，分别研究了5-氨基间苯二甲酸(H2AIP)和乙酸铜或乙酸钴的机械化学反应。结果表明，当在振荡式球磨机(20 Hz)中球磨30 min促使生成2维聚合物：[Cu(HAIP)2]?H2O和[Co(HAIP)2(H2O)2]?2H2O。
採用振盪式毬磨機作為機械能髮生裝置，分彆研究瞭5-氨基間苯二甲痠(H2AIP)和乙痠銅或乙痠鈷的機械化學反應。結果錶明，噹在振盪式毬磨機(20 Hz)中毬磨30 min促使生成2維聚閤物：[Cu(HAIP)2]?H2O和[Co(HAIP)2(H2O)2]?2H2O。
채용진탕식구마궤작위궤계능발생장치，분별연구료5-안기간분이갑산(H2AIP)화을산동혹을산고적궤계화학반응。결과표명，당재진탕식구마궤(20 Hz)중구마30 min촉사생성2유취합물：[Cu(HAIP)2]?H2O화[Co(HAIP)2(H2O)2]?2H2O。
In a shaking ball mill , the mechanochemical reactions between 5-aminoisophthalic acid and Cu(OAc)2?H2O or Co(OAc)2?4H2O have been studied. The results show that ball milling of the starting materials in the shaking (at 20 Hz) ball mill, two bidimensional coordination compounds, [Cu(HAIP)2]?H2O and [Co(HAIP)2(H2O)2]?2H2O are obtained successfully under neat granding.
