CAJ | 학술논문

采用缓慢蒸发溶剂的方法，在去离子水中合成了单核Mn（Ⅱ）配合物[Mn（phen）2（H2O）2]·（H2O）6·SO4（phen=1,10-邻菲罗啉）。利用X射线单晶衍射和元素分析等表征手段确定了其结构和组成。该配合物属于三斜晶系，空间群为P-1。该配合物的中心离子为Mn（Ⅱ），中心离子与两个1,10-邻菲罗啉和两个水分子配位，在晶胞中还有六个未配位的水分子和一个自由的硫酸根离子。配合物中存在多种结构的氢键，包括平面三角形、四面体形、四边形、五边形和六边形。
채용완만증발용제적방법，재거리자수중합성료단핵Mn（Ⅱ）배합물[Mn（phen）2（H2O）2]·（H2O）6·SO4（phen=1,10-린비라람）。이용X사선단정연사화원소분석등표정수단학정료기결구화조성。해배합물속우삼사정계，공간군위P-1。해배합물적중심리자위Mn（Ⅱ），중심리자여량개1,10-린비라람화량개수분자배위，재정포중환유륙개미배위적수분자화일개자유적류산근리자。배합물중존재다충결구적경건，포괄평면삼각형、사면체형、사변형、오변형화륙변형。
The Mn(Ⅱ) mononuclear complex [Mn(phen)2(H2O)2]·(H2O)6·SO4(phen=1,10-phenanthroline) was synthesized in deionized water by slow evaporation of the solvent. The structure and composition were characterized by X-ray crystal diffraction and elemental analysis, etc. The crystal of the complex can crystallize in triclinic system with a space group of P-1. The complex central ion is Mn (II), it coordinates with two 1,10-phenanthroline and two water molecules. In the unit, there are six un-coordinating water molecules and a free sulfate ion. There are many hydrogen bonds with various structures, including plane triangle, tetrahedron, quadrangle, pentagon and hexagon.