CAJ | 학술논문

　　以锡作捕集剂，通过调整试金配料，将熔矿温度提高到1100℃，解决了锡试金熔炼困难、不易成扣和扣回收不稳定现象。通过增加助熔剂和覆盖剂，改进了熔渣流动性及样品溢出的问题。对捕集了贵金属的锡扣用盐酸溶解锡、镍等，过滤后王水溶解金、铂、钯沉淀物，并用电感耦合等离子体质谱法测定。对国家标准物质的分析结果与标准值相一致，各元素的RSD在5%~14%之间。对5个地质样品进行结果比对，采用锡试金法与铅试金法前处理测得的金、铂、钯结果相符。该方法在生产实践中已得到了应用，适用于地质样品中金、铂、钯的分析。
　　이석작포집제，통과조정시금배료，장용광온도제고도1100℃，해결료석시금용련곤난、불역성구화구회수불은정현상。통과증가조용제화복개제，개진료용사류동성급양품일출적문제。대포집료귀금속적석구용염산용해석、얼등，과려후왕수용해금、박、파침정물，병용전감우합등리자체질보법측정。대국가표준물질적분석결과여표준치상일치，각원소적RSD재5%~14%지간。대5개지질양품진행결과비대，채용석시금법여연시금법전처리측득적금、박、파결과상부。해방법재생산실천중이득도료응용，괄용우지질양품중금、박、파적분석。
The difficulties of tin melting and the button recovery instability were solved by using the trapping agent of tin, adjusting the assay ingredient and increasing the molten ore temperature to 1100℃. Meanwhile, the slag fluidity and the overflow of the sample were improved by adding the flux and covering agent. Tin button with precious metal was dissolved and filtered, then the residue was dissolved with aqua regia and diluted with water. Au, Pt and Pd were determined by ICP-MS. The analysis results were consisted with standard values of the national standard reference materials, and the RSD value was 5%~14%. Au, Pt and Pd in geological samples were determined with tin fire assay method and lead fire assay method respectively, and their results are consistent. This method is suitable for the determination of Au, Pt and Pd in geological samples.