贵金属
貴金屬
귀금속
PRECIOUS METALS
2013年
2期
35-39
,共5页
董守安%杨辅龙%苏琳琳%方卫
董守安%楊輔龍%囌琳琳%方衛
동수안%양보룡%소림림%방위
金属材料%光化学还原%金纳米粒子%丙酮%整形
金屬材料%光化學還原%金納米粒子%丙酮%整形
금속재료%광화학환원%금납미입자%병동%정형
metal material%photochemical reduction%gold nanoparticle%acetone%reshaping
在HAuCl4-葡萄糖-丙酮体系中,丙酮不仅能起光敏剂、加速光化学还原Au(III)离子的反应,还能诱导已形成的金纳米粒子整形。整形过程伴随着明显的可见/近红外吸收光谱变化,并形成一些全新的纳米结构。实验结果表明,金纳米粒子的整形方式与初始金纳米粒子的形貌密切相关,对于球形的金纳米粒子,整形后形成纳米线;而对于锥形纳米粒子则形成金纳米片。
在HAuCl4-葡萄糖-丙酮體繫中,丙酮不僅能起光敏劑、加速光化學還原Au(III)離子的反應,還能誘導已形成的金納米粒子整形。整形過程伴隨著明顯的可見/近紅外吸收光譜變化,併形成一些全新的納米結構。實驗結果錶明,金納米粒子的整形方式與初始金納米粒子的形貌密切相關,對于毬形的金納米粒子,整形後形成納米線;而對于錐形納米粒子則形成金納米片。
재HAuCl4-포도당-병동체계중,병동불부능기광민제、가속광화학환원Au(III)리자적반응,환능유도이형성적금납미입자정형。정형과정반수착명현적가견/근홍외흡수광보변화,병형성일사전신적납미결구。실험결과표명,금납미입자적정형방식여초시금납미입자적형모밀절상관,대우구형적금납미입자,정형후형성납미선;이대우추형납미입자칙형성금납미편。
Acetone as a photosensitizer could not only accelerate the photochemical reduction reaction of Au(III), but also induce the reshaping of gold nanoparticles formed in HAuCl4-glucose-acetone solution system. The whole reshaping process was accompanied by the obvious Vis/NIR spectral changes of gold nanopartilces, finally, some new nanostructures were formed. The experimental results showed that the reshaping pattern was closely related to the original morphology of gold nanoparticles. Spherical gold nanoparticles were reshaped to gold nanolines, while gold nano-pyramids to nanodisk.