中国环境科学
中國環境科學
중국배경과학
CHINA ENVIRONMENTAL SCIENCE
2014年
4期
1012-1018
,共7页
程劲竹%郭沛涌%刘宁%陆晓昊%路丁%万禁禁
程勁竹%郭沛湧%劉寧%陸曉昊%路丁%萬禁禁
정경죽%곽패용%류저%륙효호%로정%만금금
水库%沉积物%黑碳%磷形态%吸附作用
水庫%沉積物%黑碳%燐形態%吸附作用
수고%침적물%흑탄%린형태%흡부작용
reservoir%sediments%black carbon%phosphorus speciation%adsorption
对亚热带水库福建山美水库表层沉积物黑碳的时空分布特征及其对不同形态磷的影响进行了研究.结果表明,山美水库表层沉积物黑碳(BC)含量为2.44~5.28g/kg,与国外研究水库水平相当,显著高于国内外海岸带沉积物黑碳水平.黑碳整体分布特征为:丰水期>枯水期,入库区>库尾>近坝区>库中.沉积物中黑碳与总有机碳呈现显著的正相关性,与沉积物粒径分布无明显相关关系.黑碳与有机碳比值平均为24.95%,表明黑碳来源复杂,是陆源生物质燃烧和化石燃料燃烧的共同结果.黑碳与有机磷和铁铝结合态磷这两种易释放磷之间显著相关,其对有机磷和铁铝结合态磷具有一定的吸附固定作用,这种吸附作用可能对沉积物内源磷释放具有一定的抑制效应.
對亞熱帶水庫福建山美水庫錶層沉積物黑碳的時空分佈特徵及其對不同形態燐的影響進行瞭研究.結果錶明,山美水庫錶層沉積物黑碳(BC)含量為2.44~5.28g/kg,與國外研究水庫水平相噹,顯著高于國內外海岸帶沉積物黑碳水平.黑碳整體分佈特徵為:豐水期>枯水期,入庫區>庫尾>近壩區>庫中.沉積物中黑碳與總有機碳呈現顯著的正相關性,與沉積物粒徑分佈無明顯相關關繫.黑碳與有機碳比值平均為24.95%,錶明黑碳來源複雜,是陸源生物質燃燒和化石燃料燃燒的共同結果.黑碳與有機燐和鐵鋁結閤態燐這兩種易釋放燐之間顯著相關,其對有機燐和鐵鋁結閤態燐具有一定的吸附固定作用,這種吸附作用可能對沉積物內源燐釋放具有一定的抑製效應.
대아열대수고복건산미수고표층침적물흑탄적시공분포특정급기대불동형태린적영향진행료연구.결과표명,산미수고표층침적물흑탄(BC)함량위2.44~5.28g/kg,여국외연구수고수평상당,현저고우국내외해안대침적물흑탄수평.흑탄정체분포특정위:봉수기>고수기,입고구>고미>근패구>고중.침적물중흑탄여총유궤탄정현현저적정상관성,여침적물립경분포무명현상관관계.흑탄여유궤탄비치평균위24.95%,표명흑탄래원복잡,시륙원생물질연소화화석연료연소적공동결과.흑탄여유궤린화철려결합태린저량충역석방린지간현저상관,기대유궤린화철려결합태린구유일정적흡부고정작용,저충흡부작용가능대침적물내원린석방구유일정적억제효응.
Temporal and spatial distributions of black carbon in surface sediments of a subtropical reservoir were investigated and the effects of black carbon on different phosphorous species were explored as a case study of Shanmei Reservoir in Fujian Province. The mass concentrations of black carbon (BC) in surface sediments were 2.44to 5.28g/kg in Shanmei Reservoir, which higher than those in coastal sediment. It was consistent with the results from the studies on reservoirs abroad. Overall, the BC concentrations were higher in wet season than in dry season. There were highest BC concentrations at the inlet area followed in order by those at the tail area, the dam nearby area and the middle area of the reservoir. The concentrations of black carbon had a significantly positive correlation with the concentrations of total organic carbon in the sediments, but no correlation with particle size. The ratio of black carbon to organic carbon was averaged as 24.95%, which indicated that the BC source was complex, and it commonly originated from terrestrial biomass combustion and combustion of fossil fuels. Black carbon and two active species of phosphorus (organic phosphorus and iron/aluminum bound phosphorus) were correlated significantly. Black carbon had a certain fixation to absorb these phosphorus forms, which would cause certain inhibition on the release of sediment phosphorus.