地球化学
地毬化學
지구화학
GEOCHIMICA
2014年
2期
131-140
,共10页
曹华文%张寿庭%高永璋%马莹%曾昭法%高峰%邹灏
曹華文%張壽庭%高永璋%馬瑩%曾昭法%高峰%鄒灝
조화문%장수정%고영장%마형%증소법%고봉%추호
水头萤石矿%地质特征%稀土元素%矿床成因%内蒙古林西
水頭螢石礦%地質特徵%稀土元素%礦床成因%內矇古林西
수두형석광%지질특정%희토원소%광상성인%내몽고림서
Shuitou fluorite deposit%geological features%REE%ore genesis%Linxi,Inner Mongolia
内蒙古林西县萤石矿产资源丰富,已知萤石矿床(点)68处。萤石矿床产出于中生界火山-沉积岩地层中,矿体主要受近 SN 向或 NNE 向断裂破碎带控制。为了研究水头地区萤石矿床的成矿流体来源和成矿机理,文章对矿床稀土元素进行了分析。结果表明萤石和方解石的稀土元素总量(∑REE)为4.37~159μg/g, LREE/HREE比值为0.24~1.80,δEu =0.57~1.60,具弱Ce负异常(0.81~0.98)特征, Y/Ho比值为21~78,平均41。从成矿早阶段到晚阶段,∑REE值及LREE/HREE比值均逐渐减小,晚阶段萤石具有重新活化、重结晶的特征。结合赋矿地层及矿区外围花岗岩体REE特征分析,认为其成矿流体迁移距离较远,稀土元素和成矿元素可能来自下伏高F地体和含Ca赋矿火山-沉积地层,为热液成因-破碎带充填交代型萤石矿床。
內矇古林西縣螢石礦產資源豐富,已知螢石礦床(點)68處。螢石礦床產齣于中生界火山-沉積巖地層中,礦體主要受近 SN 嚮或 NNE 嚮斷裂破碎帶控製。為瞭研究水頭地區螢石礦床的成礦流體來源和成礦機理,文章對礦床稀土元素進行瞭分析。結果錶明螢石和方解石的稀土元素總量(∑REE)為4.37~159μg/g, LREE/HREE比值為0.24~1.80,δEu =0.57~1.60,具弱Ce負異常(0.81~0.98)特徵, Y/Ho比值為21~78,平均41。從成礦早階段到晚階段,∑REE值及LREE/HREE比值均逐漸減小,晚階段螢石具有重新活化、重結晶的特徵。結閤賦礦地層及礦區外圍花崗巖體REE特徵分析,認為其成礦流體遷移距離較遠,稀土元素和成礦元素可能來自下伏高F地體和含Ca賦礦火山-沉積地層,為熱液成因-破碎帶充填交代型螢石礦床。
내몽고림서현형석광산자원봉부,이지형석광상(점)68처。형석광상산출우중생계화산-침적암지층중,광체주요수근 SN 향혹 NNE 향단렬파쇄대공제。위료연구수두지구형석광상적성광류체래원화성광궤리,문장대광상희토원소진행료분석。결과표명형석화방해석적희토원소총량(∑REE)위4.37~159μg/g, LREE/HREE비치위0.24~1.80,δEu =0.57~1.60,구약Ce부이상(0.81~0.98)특정, Y/Ho비치위21~78,평균41。종성광조계단도만계단,∑REE치급LREE/HREE비치균축점감소,만계단형석구유중신활화、중결정적특정。결합부광지층급광구외위화강암체REE특정분석,인위기성광류체천이거리교원,희토원소화성광원소가능래자하복고F지체화함Ca부광화산-침적지층,위열액성인-파쇄대충전교대형형석광상。
Fluorite is enormously rich in the Linxi County, Inner Mongolia, with 68 deposits (occurrences) so far recognized. Fluorite deposits are hosted in the strata of the Mesozoic volcano-sedimentary, the orebodies are controlled by the rupture and fracture zones near SN or NNE dipping. In this article, REEs of the fluorites and calcites were analyzed to explain the source of the ore-forming fluids and the metallogenic mechanism. The results are ∑REE, 4.37-159 μg/g, ∑LREE/∑HREE, 0.24-1.80, δEu, 0.57-1.60, Y/Ho, 21-78 (with an average of 41), with weak Ce anomaly (0.81-0.98). The values of both ∑REE and ∑LREE/∑HREE decrease gradually from the early to late metallogenic stages. Fluorites at the late stage are of the characteristic of remobilization and recrystallization. Integrating the REE analysis of the strata and related granites, the authors come to the conclusion that the fluorite-forming fluids are migrating at a far distance, REEs and ore-forming elements are from the F-rich terrane and the Ca-rich strata of volcano-sedimentary, the ore deposits are belonging to the hydrothermal type fracture filled metasomatic type.