高师理科学刊
高師理科學刊
고사이과학간
JOURNAL OF SCIENCE OF TEACHERS' COLLEGE AND UNIVERSITY
2014年
2期
61-64
,共4页
沉淀滴定%副反应系数%条件稳定常数%滴定曲线方程
沉澱滴定%副反應繫數%條件穩定常數%滴定麯線方程
침정적정%부반응계수%조건은정상수%적정곡선방정
precipitation titration%side reaction coefficient%conditional stability constant%titration curve equation
把离子强度效应、酸效应、沉淀效应、配位效应等看作是主反应发生的副反应,通过物料平衡、条件稳定常数和滴定分数等推导出沉淀滴定的林邦滴定曲线方程,为用林邦滴定曲线方程研究沉淀滴定分析理论打下坚实的基础。
把離子彊度效應、痠效應、沉澱效應、配位效應等看作是主反應髮生的副反應,通過物料平衡、條件穩定常數和滴定分數等推導齣沉澱滴定的林邦滴定麯線方程,為用林邦滴定麯線方程研究沉澱滴定分析理論打下堅實的基礎。
파리자강도효응、산효응、침정효응、배위효응등간작시주반응발생적부반응,통과물료평형、조건은정상수화적정분수등추도출침정적정적림방적정곡선방정,위용림방적정곡선방정연구침정적정분석이론타하견실적기출。
Ionic strength effect,acid effect,precipitation effect and ligand effect were identified as side reactions of the main reaction,Ringbom titration curve equation of precipitation titration was derived by means of material balance, conditional stability constant and titration scores,etc,which can lay a solid foundation for researching precipitation titration analysis theory on the basis of Ringbom titration curve equation.