高师理科学刊
高師理科學刊
고사이과학간
JOURNAL OF SCIENCE OF TEACHERS' COLLEGE AND UNIVERSITY
2014年
2期
57-60
,共4页
铁修饰的炭化树脂%诺氟沙星%吸附
鐵脩飾的炭化樹脂%諾氟沙星%吸附
철수식적탄화수지%낙불사성%흡부
Fe modified carbonized resin%norfloxacin%desorption
以阳离子交换树脂和氯化亚铁为原料,经离子交换、炭化工序,制备铁修饰的炭化树脂作为吸附剂.通过对水溶液中诺氟沙星吸附实验的初步结果表明,对诺氟沙星的吸附量可达40.49 mg/g.分别用Langmuir和Freundlich方程拟合吸附平衡数据.考察了吸附时间、pH、诺氟沙星浓度及温度等实验条件对吸附效率的影响.在吸附时间3 h、pH6、诺氟沙星初始质量浓度10 mg/L、室温条件下,铁修饰的炭化树脂吸附诺氟沙星的能力较好.诺氟沙星在铁修饰的炭化树脂上的吸附均符合准二级动力学模型.吸附过程为放热过程,吸附等温线符合Freundlich方程.
以暘離子交換樹脂和氯化亞鐵為原料,經離子交換、炭化工序,製備鐵脩飾的炭化樹脂作為吸附劑.通過對水溶液中諾氟沙星吸附實驗的初步結果錶明,對諾氟沙星的吸附量可達40.49 mg/g.分彆用Langmuir和Freundlich方程擬閤吸附平衡數據.攷察瞭吸附時間、pH、諾氟沙星濃度及溫度等實驗條件對吸附效率的影響.在吸附時間3 h、pH6、諾氟沙星初始質量濃度10 mg/L、室溫條件下,鐵脩飾的炭化樹脂吸附諾氟沙星的能力較好.諾氟沙星在鐵脩飾的炭化樹脂上的吸附均符閤準二級動力學模型.吸附過程為放熱過程,吸附等溫線符閤Freundlich方程.
이양리자교환수지화록화아철위원료,경리자교환、탄화공서,제비철수식적탄화수지작위흡부제.통과대수용액중낙불사성흡부실험적초보결과표명,대낙불사성적흡부량가체40.49 mg/g.분별용Langmuir화Freundlich방정의합흡부평형수거.고찰료흡부시간、pH、낙불사성농도급온도등실험조건대흡부효솔적영향.재흡부시간3 h、pH6、낙불사성초시질량농도10 mg/L、실온조건하,철수식적탄화수지흡부낙불사성적능력교호.낙불사성재철수식적탄화수지상적흡부균부합준이급동역학모형.흡부과정위방열과정,흡부등온선부합Freundlich방정.
With cation exchange resin and ferrous chloride as raw material,through ion exchange,carbonization process,the preparation of iron modified carbonized resins as adsorbent.In aqueous solution of norfloxacin adsorption experiment of the preliminary results show that the adsorption quantity of norfloxacin is up to 40.49 mg/g. With the Langmuir and Freundlich equation of adsorption equilibrium data fitting.The effects of experimental parameters such as adsorption time,pH,NOR concentrationand temperature on the adsorption efficiency have been investigated.The adsorption capacity of NOR with iron modified carbonized resin is better under the conditions of adsorption time 3 h, pH 6,NOR concentration 10.0 mg/L,room temperature.The adsorption of NOR with the adsorbent follows the pseudo-second-order kinetics model.The adsorption process is an exothermic one,and the desorption data can be fitted with Freundlich isotherm models.