CAJ | 학술논문

以丙烯酸甲酯、甲基丙烯酸乙酯、丙烯酸丁酯、2-丙烯酰胺基-2-甲基丙磺酸以及纳米TiO2为主要原料，采用种子乳液聚合法制备了纳米TiO2核壳型聚丙烯酸酯乳液黏合剂，通过FT-IR谱、TEM观测、DSC分析、粒度分析等对其结构进行表征，测试并探讨了其用于涂料印花后的织物性能。结果表明，FT-IR谱分析得到各种单体之间发生了共聚反应；DSC测试结果和TEM照片都显示乳液黏合剂为明显的核-壳结构物质；粒度分析得到乳液黏合剂的粒径大小主要分布在100 nm以内；纳米TiO2核壳型黏合剂作用后的织物各项牢度均有较明显的提高，干、湿摩擦牢度可达4~5级，刷洗牢度、皂洗牢度均可达4级，且涂料印花后手感柔软、光洁滑爽、弹性好。
이병희산갑지、갑기병희산을지、병희산정지、2-병희선알기-2-갑기병광산이급납미TiO2위주요원료，채용충자유액취합법제비료납미TiO2핵각형취병희산지유액점합제，통과FT-IR보、TEM관측、DSC분석、립도분석등대기결구진행표정，측시병탐토료기용우도료인화후적직물성능。결과표명，FT-IR보분석득도각충단체지간발생료공취반응；DSC측시결과화TEM조편도현시유액점합제위명현적핵-각결구물질；립도분석득도유액점합제적립경대소주요분포재100 nm이내；납미TiO2핵각형점합제작용후적직물각항뇌도균유교명현적제고，간、습마찰뇌도가체4~5급，쇄세뇌도、조세뇌도균가체4급，차도료인화후수감유연、광길활상、탄성호。
With methyl acrylate, ethyl methacrylate, butyl acrylate, 2-acrylamide-2-methyl propane sulfonic acid and nano-TiO2 as the main raw materials, nano-TiO2 core-shell polyacrylate emulsion adhesive was prepared by seed emulsion polymerization. And its structure was characterized by FT-IR, TEM and DSC, and the perfor-mance of fabric after pigment printing by this adhesive was tested and discussed. The results show that FT-IR spectrum analysis can obtain the copolymerization reaction among various monomer; the test results of DSC and im-ages of TEM indicate that emulsion adhesive is obvious core-shell structure material; the grain size analysis can obtain that particle size of emulsion adhesive is mainly distributed in less than 100 nm; the various fastness of fabrics after using nano-TiO2 core-shell adhesive obviously increases, the dry and wet rubbing fastness can reach level 4~5, and brushing fastness,soaping fastness can reach level 4. At the same time, it can obtain soft hand, bright and clean surface, smooth feel and good elasticity after pigment printing.