农业环境科学学报
農業環境科學學報
농업배경과학학보
Journal of Agro-Environment Science
2014年
6期
1082-1088
,共7页
尹德良%何天容%安艳玲%罗光俊%阳许%陈筠
尹德良%何天容%安豔玲%囉光俊%暘許%陳筠
윤덕량%하천용%안염령%라광준%양허%진균
万山%汞矿区%稻米总汞%土壤性质%相关性
萬山%汞礦區%稻米總汞%土壤性質%相關性
만산%홍광구%도미총홍%토양성질%상관성
Wanshan%Hg-mining areas%rice THg%soil properties%correlation
运用冷原子荧光技术(CVAFS)对贵州万山汞矿区主要河流范围内稻米总汞(THg)含量进行了测定,并从区域层面对稻米THg的分布特征及影响因素进行了研究。结果表明:万山汞矿区主要流域内稻米THg含量范围为2.838~295.534 ng·g-1,平均含量为50.819 ng·g-1,67.5%的样品已经超出GB 2762-2005中所规定的粮食污染物限量标准20 ng·g-1(总汞)。在水平空间分布上,6个检测区域的稻米THg含量均随着与汞矿核心区距离加大而降低,但是不同区域之间的降低变化幅度不尽相同。通过对稻米THg与土壤THg、SiO2、Al2O3、总铁(TFe2O3)、总硫(TS)、总磷(TP)、总氮(TN)、有机质、pH进行相关性分析发现,稻米THg与TS、TN、有机质、pH表现出显著的正相关性,与SiO2显著性负相关,但未发现与土壤THg之间有显著的相关性。
運用冷原子熒光技術(CVAFS)對貴州萬山汞礦區主要河流範圍內稻米總汞(THg)含量進行瞭測定,併從區域層麵對稻米THg的分佈特徵及影響因素進行瞭研究。結果錶明:萬山汞礦區主要流域內稻米THg含量範圍為2.838~295.534 ng·g-1,平均含量為50.819 ng·g-1,67.5%的樣品已經超齣GB 2762-2005中所規定的糧食汙染物限量標準20 ng·g-1(總汞)。在水平空間分佈上,6箇檢測區域的稻米THg含量均隨著與汞礦覈心區距離加大而降低,但是不同區域之間的降低變化幅度不儘相同。通過對稻米THg與土壤THg、SiO2、Al2O3、總鐵(TFe2O3)、總硫(TS)、總燐(TP)、總氮(TN)、有機質、pH進行相關性分析髮現,稻米THg與TS、TN、有機質、pH錶現齣顯著的正相關性,與SiO2顯著性負相關,但未髮現與土壤THg之間有顯著的相關性。
운용랭원자형광기술(CVAFS)대귀주만산홍광구주요하류범위내도미총홍(THg)함량진행료측정,병종구역층면대도미THg적분포특정급영향인소진행료연구。결과표명:만산홍광구주요류역내도미THg함량범위위2.838~295.534 ng·g-1,평균함량위50.819 ng·g-1,67.5%적양품이경초출GB 2762-2005중소규정적양식오염물한량표준20 ng·g-1(총홍)。재수평공간분포상,6개검측구역적도미THg함량균수착여홍광핵심구거리가대이강저,단시불동구역지간적강저변화폭도불진상동。통과대도미THg여토양THg、SiO2、Al2O3、총철(TFe2O3)、총류(TS)、총린(TP)、총담(TN)、유궤질、pH진행상관성분석발현,도미THg여TS、TN、유궤질、pH표현출현저적정상관성,여SiO2현저성부상관,단미발현여토양THg지간유현저적상관성。
Total mercury(THg)concentrations in rice grains from Wanshan, Guizhou province, which was impacted by Hg mining, were mea-sured using a CVAFS method. THg concentrations in the rice grains showed a clear spatial pattern and were highly related to the inputs of Hg derived from mining. Concentrations of THg in rice grains in major basins of Hg mining ranged from 2.8 ng·g-1 to 295 ng·g-1 with an av-erage of 50.8 ng·g-1. Approximate 67.5%of rice samples showed THg concentrations exceeding the national standards(THg=20 ng·g-1). Rice THg concentrations tended to decrease from central Hg-mined areas to less polluted ones. However, the decreasing rates of THg con-centrations in rice were quite different in the six areas. Rice THg concentrations were significantly positively correlated with TS, TN, organic matter, and pH, but negatively with SiO2. Rice THg had no correlation with soil THg concentrations.