化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2014年
6期
914-917
,共4页
钼酸锰微晶%水热制备方法%X射线衍射%扫描电镜%光催化性能
鉬痠錳微晶%水熱製備方法%X射線衍射%掃描電鏡%光催化性能
목산맹미정%수열제비방법%X사선연사%소묘전경%광최화성능
molybdate manganese microcrystal%hydrothermal method%X-ray%SEM%photocatalytic performance
本文以可溶性二价锰盐和钼酸钠为原料,利用温和水热法,在低温条件下制备出了一种新形貌的钼酸锰微晶。探究水热条件下对钼酸锰微晶生长的影响。对于所制备的钼酸锰产品,用X射线衍射( XRD)测试微晶结构、扫描电子显微镜( SEM)测试微晶的颗粒尺寸,微晶形貌。在甲基橙溶液的光催化降解实验中考查其光催化性能,该光催化反应近似符合一级动力学方程,k值约为0．5 h-1。
本文以可溶性二價錳鹽和鉬痠鈉為原料,利用溫和水熱法,在低溫條件下製備齣瞭一種新形貌的鉬痠錳微晶。探究水熱條件下對鉬痠錳微晶生長的影響。對于所製備的鉬痠錳產品,用X射線衍射( XRD)測試微晶結構、掃描電子顯微鏡( SEM)測試微晶的顆粒呎吋,微晶形貌。在甲基橙溶液的光催化降解實驗中攷查其光催化性能,該光催化反應近似符閤一級動力學方程,k值約為0．5 h-1。
본문이가용성이개맹염화목산납위원료,이용온화수열법,재저온조건하제비출료일충신형모적목산맹미정。탐구수열조건하대목산맹미정생장적영향。대우소제비적목산맹산품,용X사선연사( XRD)측시미정결구、소묘전자현미경( SEM)측시미정적과립척촌,미정형모。재갑기등용액적광최화강해실험중고사기광최화성능,해광최화반응근사부합일급동역학방정,k치약위0．5 h-1。
Molybdate Manganese( MnMoO4 ) microcrytstal has been synthesized via a simple and mild hydrothermal route in the ab-sence of any external inorganic additives or organic structure-directing templates. Powder X-ray diffraction( XRD) and scanning elec-tron microscopy( SEM) are used to characterize the crystallization and particle size and morphology of the obtained MnMoO4 micro-crytstals. MnMoO4 microcrytstals are well crystallized with a uniform morphology. The photocatalytic activity is evaluated by decolor-ization of methyl orange solution under identical conditions. This reaction is nearly comply with a kinetic equation,k≈0. 5 h-1.
